Published January 1977
| Version v1
Journal article
Nitration by nitronium salts
Creators
- 1. Leningradskij Tekhnologicheskij Inst. (USSR)
Description
Nitration has been studied of aliphtic and aromatic secondary amines with nitronium tetrafluoroborate or hexafluorosilicate in acetonitrile, alcohol, acetates, ethers, and chloroalkanes. It has been established that the nature of the solvent affects only slightly the yield of N-nitroamines. In case of aromatic amines, the rearrangement N-nitro→ C-nitro can be controlled by the choice of the solvent and nitronium salt
Additional details
Additional titles
- Subtitle (English)
- 1.Nitration of secondary amines by nitronium salts
- Original title (Russian)
- Нитрование солями нитрония
- Original subtitle (Russian)
- 1.Nitrovanie vtorichnykh aminov solyami nitroniya.
Publishing Information
- Journal Title
- Zh. Org. Khim.
- Journal Volume
- 13
- Journal Issue
- 1
- Series
- Zh. Org. Khim.
- Journal Page Range
- 11-17
INIS
- Country of Publication
- USSR
- Country of Input or Organization
- USSR
- INIS RN
- 8336941
- Subject category
- S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
- Descriptors DEI
- ACETATES; ALCOHOLS; AMINES; BORON COMPOUNDS; CHEMICAL PREPARATION; CHEMICAL REACTION YIELD; CHEMICAL REACTIONS; ETHERS; NITRITES; NITROSO COMPOUNDS; PHOSPHATES; TEMPERATURE DEPENDENCE
- Descriptors DEC
- CARBOXYLIC ACID SALTS; HYDROXY COMPOUNDS; NITROGEN COMPOUNDS; ORGANIC COMPOUNDS; ORGANIC NITROGEN COMPOUNDS; ORGANIC OXYGEN COMPOUNDS; OXYGEN COMPOUNDS; PHOSPHORUS COMPOUNDS; SYNTHESIS
Optional Information
- Notes
- 14 refs.; for English translation see the journal J. Org. Chem. USSR.