Elimination of dimethyl methylphosphonate by plasma flame made of microwave plasma and burning hydrocarbon fuel
- 1. Department of Molecular Science and Technology, Ajou University, San 5, Wonchon-Dong, Youngtong-Gu, Suwon 443-749 (Korea, Republic of)
- 2. Department of Chemical and Environmental Analysis, Chemical Defense Research Institute, San 12-555, Naegok-Dong, Seocho-Gu, Seoul 137-180 (Korea, Republic of)
Description
Elimination of dimethyl methylphosphonate (DMMP) in liquid phase was studied by making use of a microwave plasma burner, exhibiting a safe removal capability of stockpiled chemical weapons. The microwave plasma burner consisted of a fuel injector and a plasma flame exit connected in series to a microwave plasma torch. The burner flames were sustained by injecting hydrocarbon fuels into the microwave plasma torch in air discharge. The Fourier transform infrared spectra indicated near perfect elimination of DMMP in the microwave plasma burner. This was confirmed by gas chromatography spectra as supporting data, revealing the disappearance of even intermediary compounds in the process of DMMP destruction. The experimental results and the physical configuration of the microwave plasma burner may provide an effective means of on-site removal of chemical warfare agents found on a battlefield
Additional details
Identifiers
- DOI
- 10.1063/1.2939799;
Publishing Information
- Journal Title
- Journal of Applied Physics
- Journal Volume
- 103
- Journal Issue
- 12
- Journal Page Range
- p. 123303-123303.4
- ISSN
- 0021-8979
- CODEN
- JAPIAU
INIS
- Country of Publication
- United States
- Country of Input or Organization
- International Atomic Energy Agency (IAEA)
- INIS RN
- 40018008
- Subject category
- S71: CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSICS;
- Descriptors DEI
- CHEMICAL WARFARE AGENTS; COMBUSTION; FLAMES; FOURIER TRANSFORMATION; GAS CHROMATOGRAPHY; HYDROCARBONS; INFRARED SPECTRA; MICROWAVE RADIATION; MILITARY EQUIPMENT; PHOSPHONATES; PLASMA
- Descriptors DEC
- CHEMICAL REACTIONS; CHROMATOGRAPHY; ELECTROMAGNETIC RADIATION; EQUIPMENT; INTEGRAL TRANSFORMATIONS; ORGANIC COMPOUNDS; ORGANIC PHOSPHORUS COMPOUNDS; OXIDATION; RADIATIONS; SEPARATION PROCESSES; SPECTRA; THERMOCHEMICAL PROCESSES; TRANSFORMATIONS; WEAPONS
Optional Information
- Notes
- (c) 2008 American Institute of Physics