Published 1979
| Version v1
Journal article
Thermodynamic functions and stability constants of rare earths with monothiodibenzoylmethane
Creators
- 1. M.A. College of Technology, Bhopal (India)
Description
The stability constants (log K) of the complexes formed between Y, La, Ce, Pr, Nd, Sm, Eu, Gd, Dy and Ho and monothiodibenzoylmethane (HSDBM) have been determined pH metrically at temperatures 30, 35 and 400C at constant 0.05 M NaClO4 ionic strength. The effect of variation of ionic strength was studied by taking three ionic strengths at 300C. The thermodynamic stability constants were determined by extrapolating log K vs μ plot at μ= 0. The other thermodynamic functions were calculated from temperature stability constant plot. The values were refined by least square method. (author)
Additional details
Publishing Information
- Journal Title
- J. Inorg. Nucl. Chem.
- Journal Volume
- 41
- Journal Issue
- 5
- Series
- J. Inorg. Nucl. Chem.
- Journal Page Range
- 717-719
- ISSN
- 0022-1902
INIS
- Country of Publication
- United Kingdom
- Country of Input or Organization
- United Kingdom
- INIS RN
- 10481695
- Subject category
- S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
- Resource subtype / Literary indicator
- Numerical Data
- Descriptors DEI
- CERIUM COMPLEXES; DYSPROSIUM COMPLEXES; ENTHALPY; ENTROPY; EUROPIUM COMPLEXES; EXPERIMENTAL DATA; FREE ENTHALPY; GADOLINIUM COMPLEXES; GRAPHS; HOLMIUM COMPLEXES; ISOLATED VALUES; LANTHANUM COMPLEXES; MEDIUM TEMPERATURE; NEODYMIUM COMPLEXES; ORGANIC SULFUR COMPOUNDS; PH VALUE; PRASEODYMIUM COMPLEXES; SAMARIUM COMPLEXES; SODIUM PERCHLORATES; STABILITY; TEMPERATURE DEPENDENCE; YTTRIUM COMPLEXES
- Descriptors DEC
- ALKALI METAL COMPOUNDS; CHLORINE COMPOUNDS; COMPLEXES; DATA; DATA FORMS; ENERGY; HALOGEN COMPOUNDS; INFORMATION; NUMERICAL DATA; ORGANIC COMPOUNDS; OXYGEN COMPOUNDS; PERCHLORATES; PHYSICAL PROPERTIES; RARE EARTH COMPLEXES; SODIUM COMPOUNDS; THERMODYNAMIC PROPERTIES; TRANSITION ELEMENT COMPLEXES