Published November 2006 | Version v1
Journal article Metadata-only

(NH3CH2CH2NH3)B6O9(OH)2: Synthesis and crystal structure of a novel layered borate templated by ethylenediamine

Creators

  • 1. Analytical Testing Centre, Zhoukou Normal University, Zhoukou 466001, Henan Province (China)
  • 2. Department of Chemistry, Zhoukou Normal University, Zhoukou 466001, Henan Province (China)

Description

A novel intercalated borate compound (NH3CH2CH2NH3)B6O9(OH)2, has been solvothermally synthesized, and structurally characterized by single crystal X-ray diffraction. Compound crystallizes in the monoclinic, space group P2(1)/c, a=8.6200(17)A, b=15.656(3)A, c=8.8386(18)A, β=93.32(3)o, V=1190.8(4)A3, Z=4. Its oxoborate structure is built up from 1-D polyborate chains with 3, 11-membered boron rings bonded diamine molecules through electrostatic attraction and hydrogen bond interactions to construct 2-D layered compound. Other characterizations by IR, element analysis, thermal analysis and specific surface area are also discussed

Additional details

Identifiers

DOI
10.1016/j.jssc.2006.04.058;
PII
S0022-4596(06)00268-4;

Publishing Information

Journal Title
Journal of Solid State Chemistry
Journal Volume
179
Journal Issue
11
Journal Page Range
p. 3265-3269
ISSN
0022-4596
CODEN
JSSCBI

INIS

Country of Publication
United States
Country of Input or Organization
International Atomic Energy Agency (IAEA)
INIS RN
38063093
Subject category
S36: MATERIALS SCIENCE;
Descriptors DEI
AMINES; BORATES; MONOCLINIC LATTICES; MONOCRYSTALS; SPACE GROUPS; SPECIFIC SURFACE AREA; SYNTHESIS; THERMAL ANALYSIS; X-RAY DIFFRACTION
Descriptors DEC
BORON COMPOUNDS; COHERENT SCATTERING; CRYSTAL LATTICES; CRYSTAL STRUCTURE; CRYSTALS; DIFFRACTION; ORGANIC COMPOUNDS; OXYGEN COMPOUNDS; PHYSICAL PROPERTIES; SCATTERING; SYMMETRY GROUPS

Optional Information

Copyright
Copyright (c) 2006 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved.