Published April 26, 2013 | Version v1
Journal article Metadata-only

Single-molecule magnetism in a single-ion triamidoamine uranium(V) terminal mono-oxo complex

Creators

  • 1. School of Chemistry, University of Nottingham (United Kingdom)
  • 2. School of Chemistry and Photon Science Institute, University of Manchester (United Kingdom)

Description

Straightforward oxidation of a triamidoamine uranium(III) complex with trimethyl-N-oxide affords a uranium(V) terminal mono-oxo complex which is the first clear-cut example of a uranium(V) single-molecule magnet (SMM). This monometallic complex unambiguously shows that a strongly axially ligated and thus anisotropic ligand field can be used to overcome the limited magnetic anisotropy of uranium(V). (Copyright copyright 2013 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim)

Availability note (English)

Available from: http://dx.doi.org/10.1002/anie.201301007

Additional details

Identifiers

DOI
10.1002/anie.201301007;

Publishing Information

Journal Title
Angewandte Chemie (International Edition)
Journal Volume
52
Journal Issue
18
Journal Page Range
p. 4921-4924
ISSN
1433-7851
CODEN
ACIEF5

INIS

Country of Publication
Germany
Country of Input or Organization
Germany
INIS RN
49004762
Subject category
S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
Descriptors DEI
AMINES; ANISOTROPY; LIGANDS; MAGNETISM; MAGNETS; ORGANOMETALLIC COMPOUNDS; OXIDATION; RELAXATION; URANIUM COMPLEXES
Descriptors DEC
ACTINIDE COMPLEXES; CHEMICAL REACTIONS; COMPLEXES; EQUIPMENT; ORGANIC COMPOUNDS

Optional Information

Notes
With 7 figs., 70 refs.