Araneose Ti³⁺ self-doping TiO₂/SiO₂ nanowires membrane for removal of aqueous MB under visible light irradiation

Araneose Ti³⁺ self-doped TiO₂/SiO₂ nanowires (RTiO₂/SiO₂) were prepared and anchored onto a polyethersulfone (PES) membrane. Careful characterizations and measurements indicated a covalent grafting of SiO₂ onto reduced TiO₂ (RTiO₂) through Ti–O–Si linkages, acquiring uniformed RTiO₂/SiO₂ nanowires of almost complete anatase and benign hydrophilicity. The RTiO₂/SiO₂-based PES membrane showed a significantly enhanced visible light–driven degradation rate of methylene blue (MB) (90.7%), compared with that on bare PES (11.1%) and PES-RTiO₂ (59.6%) membranes. The residual MB in filtered water was less than 5% after reusing three times. The normalized permeate flux of the modified membrane was 0.83, and the transmembrane pressure only increased by 0.4 MPa under irradiation of visible light. The improved performance of the PES-RTiO₂/SiO₂ was attributed to efficient intercept of MB molecular, light harvesting of visible light, and separation of charge carriers on araneose RTiO₂/SiO₂ nanowires.