Published March 2007
| Version v1
Journal article
Experimental and theoretical study of S 2p and C 1s generalized oscillator strengths in CS2
Creators
- 1. Instituto de Quimica, Univ. Fed. do Rio de Janeiro, Rio de Janeiro, RJ 21949-900 (Brazil)
- 2. Department of Physics and Astronomy, McMaster University, Ont. L8S 4M1 (Canada)
- 3. Department of Chemistry, McMaster University, Hamilton, Ont. L8S 4M1 (Canada)
Description
The generalized oscillator strength profiles in the momentum transfer range (K) of (2 a.u.-2 < K2 < 30 a.u.-2) for the most intense resolved S 2p, and C 1s transitions of carbon disulfide (CS2) are presented. Optical oscillator strengths and generalized oscillator strength profiles have been calculated for vertical excitation from the ground X1Σg+ electronic state to several C(1s) and S(2p) inner-shell electronic excited states of CS2, using high level ab initio (HF-CI) calculations. The experimental and computed GOS profiles of CS2 are compared and found to be generally in reasonable agreement
Additional details
Identifiers
- DOI
- 10.1016/j.elspec.2006.12.001;
- PII
- S0368-2048(06)00211-8;
Publishing Information
- Journal Title
- Journal of Electron Spectroscopy and Related Phenomena
- Journal Volume
- 155
- Journal Issue
- 1-3
- Journal Page Range
- p. 21-27
- ISSN
- 0368-2048
- CODEN
- JESRAW
Conference
- Title
- International symposium on scattering, coincidence and absorption studies of molecules (SCASM)
- Dates
- 4-6 Sep 2006
- Place
- Rio de Janeiro (Brazil)
INIS
- Country of Publication
- Netherlands
- Country of Input or Organization
- International Atomic Energy Agency (IAEA)
- INIS RN
- 39083173
- Subject category
- S74: ATOMIC AND MOLECULAR PHYSICS;
- Resource subtype / Literary indicator
- Conference
- Descriptors DEI
- CARBON SULFIDES; CESIUM SULFIDES; DISULFIDES; EXCITED STATES; HYDROFLUORIC ACID; INNER-SHELL EXCITATION; MOLECULES; MOMENTUM TRANSFER; OSCILLATOR STRENGTHS
- Descriptors DEC
- ALKALI METAL COMPOUNDS; CARBON COMPOUNDS; CESIUM COMPOUNDS; CHALCOGENIDES; ENERGY LEVELS; ENERGY-LEVEL TRANSITIONS; EXCITATION; FLUORINE COMPOUNDS; HALOGEN COMPOUNDS; HYDROGEN COMPOUNDS; INORGANIC ACIDS; INORGANIC COMPOUNDS; ORGANIC COMPOUNDS; ORGANIC SULFUR COMPOUNDS; SULFIDES; SULFUR COMPOUNDS
Optional Information
- Copyright
- Copyright (c) 2006 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved.