Published February 2005 | Version v1
Journal article

Excess molar enthalpies of the ternary mixtures: (methyl tert-butyl ether or 2-methyltetrahydrofuran + cyclohexane + 2,2,4-trimethylpentane) at the temperature 298.15 K

  • 1. Department of Chemical Engineering, University of Ottawa, Ottawa, Ont., K1N 6N5 (Canada)

Description

Measurements of excess molar enthalpies at the temperature T = 298.15 K in a flow microcalorimeter, are reported for the two ternary mixtures {x1(C5H12O or C5H10O) + x2cC6H6 + x3(CH3)2CHCH2C(CH3)3} by mixing component 1 with binary mixtures of components 2 and 3. Smooth representations of the ternary results are presented and used to construct constant excess molar enthalpy contours on Roozeboom diagrams. The application of the Liebermann and Fried model to predict ternary excess enthalpies yielded approximate but correct trend of variation with concentration and the presence of an internal maximum in both ternary systems, using only the physical properties of the components and their binary mixtures

Additional details

Identifiers

DOI
10.1016/j.jct.2004.09.003;
PII
S0021-9614(04)00188-0;

Publishing Information

Journal Title
Journal of Chemical Thermodynamics
Journal Volume
37
Journal Issue
2
Journal Page Range
p. 181-186
ISSN
0021-9614
CODEN
JCTDAF

Optional Information

Copyright
Copyright (c) 2004 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved.