Published February 2005
| Version v1
Journal article
Excess molar enthalpies of the ternary mixtures: (methyl tert-butyl ether or 2-methyltetrahydrofuran + cyclohexane + 2,2,4-trimethylpentane) at the temperature 298.15 K
Creators
- 1. Department of Chemical Engineering, University of Ottawa, Ottawa, Ont., K1N 6N5 (Canada)
Description
Measurements of excess molar enthalpies at the temperature T = 298.15 K in a flow microcalorimeter, are reported for the two ternary mixtures {x1(C5H12O or C5H10O) + x2cC6H6 + x3(CH3)2CHCH2C(CH3)3} by mixing component 1 with binary mixtures of components 2 and 3. Smooth representations of the ternary results are presented and used to construct constant excess molar enthalpy contours on Roozeboom diagrams. The application of the Liebermann and Fried model to predict ternary excess enthalpies yielded approximate but correct trend of variation with concentration and the presence of an internal maximum in both ternary systems, using only the physical properties of the components and their binary mixtures
Additional details
Identifiers
- DOI
- 10.1016/j.jct.2004.09.003;
- PII
- S0021-9614(04)00188-0;
Publishing Information
- Journal Title
- Journal of Chemical Thermodynamics
- Journal Volume
- 37
- Journal Issue
- 2
- Journal Page Range
- p. 181-186
- ISSN
- 0021-9614
- CODEN
- JCTDAF
INIS
- Country of Publication
- United Kingdom
- Country of Input or Organization
- International Atomic Energy Agency (IAEA)
- INIS RN
- 36074272
- Subject category
- S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
- Descriptors DEI
- BINARY MIXTURES; BUTYL ETHER; CALORIMETERS; CYCLOHEXANE; DIAGRAMS; ENTHALPY; MIXING; MTHF; TEMPERATURE RANGE 0273-0400 K
- Descriptors DEC
- ALKANES; CYCLOALKANES; DISPERSIONS; ETHERS; FURANS; HETEROCYCLIC COMPOUNDS; HYDROCARBONS; INFORMATION; MEASURING INSTRUMENTS; MIXTURES; ORGANIC COMPOUNDS; ORGANIC OXYGEN COMPOUNDS; PHYSICAL PROPERTIES; TEMPERATURE RANGE; TETRAHYDROFURAN; THERMODYNAMIC PROPERTIES
Optional Information
- Copyright
- Copyright (c) 2004 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved.