Published April 2008 | Version v1
Journal article

Densities and volumetric properties of (N-(2-hydroxyethyl)morpholine + ethanol, + 1-propanol, + 2-propanol, + 1-butanol, and + 2-butanol) at (293.15, 298.15, 303.15, 313.15, and 323.15) K

  • 1. Industrial Chemistry Centre, Royal Scientific Society, P.O. Box 1438, Aljubaiha, Amman 11941 (Jordan)
  • 2. Chemical and Pharmaceutical Engineering, German-Jordanian University, P.O. Box 35247, Amman 11180 (Jordan)
  • 3. Ministry of Science and Technology, Jadiriyah, P.O. Box 10039, Baghdad (Iraq)

Description

Densities of binary mixtures of N-(2-hydroxyethyl)morpholine with ethanol, 1-propanol, 2-propanol, 1-butanol, and 2-butanol were measured over the entire composition range at temperatures from (293.15 to 323.15) K and atmospheric pressure using a vibrating-tube densimeter. The excess molar volumes, VE were calculated from density data and fitted to the Redlich-Kister polynomial equation. Apparent molar volumes, partial molar volume at infinite dilution and the thermal expansion coefficient of the mixtures were also calculated. The VE values were found to be negative over the entire composition range and at all temperatures studied and become less negative with increasing carbon chain length of the alkanols

Availability note (English)

Available from http://dx.doi.org/10.1016/j.jct.2007.11.010

Additional details

Identifiers

DOI
10.1016/j.jct.2007.11.010;
PII
S0021-9614(07)00231-5;

Publishing Information

Journal Title
Journal of Chemical Thermodynamics
Journal Volume
40
Journal Issue
4
Journal Page Range
p. 592-598
ISSN
0021-9614
CODEN
JCTDAF

Optional Information

Copyright
Copyright (c) 2007 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved.