Published April 2008
| Version v1
Journal article
Densities and volumetric properties of (N-(2-hydroxyethyl)morpholine + ethanol, + 1-propanol, + 2-propanol, + 1-butanol, and + 2-butanol) at (293.15, 298.15, 303.15, 313.15, and 323.15) K
- 1. Industrial Chemistry Centre, Royal Scientific Society, P.O. Box 1438, Aljubaiha, Amman 11941 (Jordan)
- 2. Chemical and Pharmaceutical Engineering, German-Jordanian University, P.O. Box 35247, Amman 11180 (Jordan)
- 3. Ministry of Science and Technology, Jadiriyah, P.O. Box 10039, Baghdad (Iraq)
Description
Densities of binary mixtures of N-(2-hydroxyethyl)morpholine with ethanol, 1-propanol, 2-propanol, 1-butanol, and 2-butanol were measured over the entire composition range at temperatures from (293.15 to 323.15) K and atmospheric pressure using a vibrating-tube densimeter. The excess molar volumes, VE were calculated from density data and fitted to the Redlich-Kister polynomial equation. Apparent molar volumes, partial molar volume at infinite dilution and the thermal expansion coefficient of the mixtures were also calculated. The VE values were found to be negative over the entire composition range and at all temperatures studied and become less negative with increasing carbon chain length of the alkanols
Availability note (English)
Available from http://dx.doi.org/10.1016/j.jct.2007.11.010Additional details
Identifiers
- DOI
- 10.1016/j.jct.2007.11.010;
- PII
- S0021-9614(07)00231-5;
Publishing Information
- Journal Title
- Journal of Chemical Thermodynamics
- Journal Volume
- 40
- Journal Issue
- 4
- Journal Page Range
- p. 592-598
- ISSN
- 0021-9614
- CODEN
- JCTDAF
INIS
- Country of Publication
- United Kingdom
- Country of Input or Organization
- International Atomic Energy Agency (IAEA)
- INIS RN
- 40016571
- Subject category
- S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
- Descriptors DEI
- APPARENT MOLAL VOLUME; ATMOSPHERIC PRESSURE; BINARY MIXTURES; BUTANOLS; DENSIMETERS; DENSITY; DILUTION; EQUATIONS; ETHANOL; PARTIAL MOLAL VOLUME; POLYNOMIALS; PROPANOLS; THERMAL EXPANSION
- Descriptors DEC
- ALCOHOLS; DISPERSIONS; EXPANSION; FUNCTIONS; HYDROXY COMPOUNDS; MEASURING INSTRUMENTS; MIXTURES; ORGANIC COMPOUNDS; PHYSICAL PROPERTIES
Optional Information
- Copyright
- Copyright (c) 2007 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved.