Kinetic evolutionary behavior of catalysis-select migration
Creators
- 1. Department of Physics, Wenzhou University, Wenzhou 325035 (China)
Description
We propose a catalysis-select migration driven evolution model of two-species (A- and B-species) aggregates, where one unit of species A migrates to species B under the catalysts of species C, while under the catalysts of species D the reaction will become one unit of species B migrating to species A. Meanwhile the catalyst aggregates of species C perform self-coagulation, as do the species D aggregates. We study this catalysis-select migration driven kinetic aggregation phenomena using the generalized Smoluchowski rate equation approach with C species catalysis-select migration rate kernel K(k;i,j) = Kkij and D species catalysis-select migration rate kernel J(k;i,j)= Jkij. The kinetic evolution behaviour is found to be dominated by the competition between the catalysis-select immigration and emigration, in which the competition is between JD0 and KC0 (D0 and C0 are the initial numbers of the monomers of species D and C, respectively). When JD0 −KC0 > 0, the aggregate size distribution of species A satisfies the conventional scaling form and that of species B satisfies a modified scaling form. And in the case of JD0−KC0 < 0, species A and B exchange their aggregate size distributions as in the above JD0−KC0 > 0 case. (interdisciplinary physics and related areas of science and technology)
Availability note (English)
Available from http://dx.doi.org/10.1088/1674-1056/21/6/068201Additional details
Identifiers
Publishing Information
- Journal Title
- Chinese Physics. B
- Journal Volume
- 21
- Journal Issue
- 6
- Journal Page Range
- [7 p.]
- ISSN
- 1674-1056
INIS
- Country of Publication
- China
- Country of Input or Organization
- International Atomic Energy Agency (IAEA)
- INIS RN
- 45029664
- Subject category
- S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
- Descriptors DEI
- AGGLOMERATION; CATALYSIS; CATALYSTS; CHEMICAL REACTION KINETICS; KERNELS; MATHEMATICAL MODELS; MIGRATION; MONOMERS
- Descriptors DEC
- KINETICS; REACTION KINETICS