Nest-like LiFePO4/C architectures for high performance lithium ion batteries

Highlights: ► Nest-like LiFePO4/C architectures (nest-like LPCs) were synthesized by solvothermal method. ► The microstructures of nest-like LPCs are very stable constructed by many nanosheets. ► The unique structures offer nest-like LPC electrode with high rate performance. ► The reversible capacity of nest-like LPCs electrode is as high as 120 mAh g−1 at 10 C. - Abstract: A novel kind of microsized nest-like LiFePO4/C architectures was synthesized by solvothermal method using inexpensive and stable Fe3+ salt as iron source and ethylene glycol as mediate. A layer of carbon could be coated directly on the surface of LiFePO4 crystals and the nest-like unique structures offer the cathode materials with high reversible capacity, excellent cycling stability and high rate performance. The reversible capacity can maintain 159 mAh g−1 at 0.1 C and 120 mAh g−1 at 10 C.