Published November 18, 1981
| Version v1
Journal article
Carbon monoxide activation by organoactinides. Migratory CO insertion into metal-hydrogen bonds to produce mononuclear formyls
Description
Spontaneous and rapid insertion of CO into certain organoactinide hydrides is reported. The sterically unencumbered bis(pentamethylcyclopentadienyl) 5f hydrides such as (Th[(CH3)5C5]2(μ-H)H)2 react rapidly with excess CO at -780C. The carbonylation of alkoxy hydroxides is also described. Thermodynamic and kinetic aspects of the reactions are reported
Additional details
Publishing Information
- Journal Title
- J. Am. Chem. Soc.
- Journal Volume
- 103
- Journal Issue
- 23
- Series
- J. Am. Chem. Soc.
- Journal Page Range
- 6959-6962
- ISSN
- 0002-7863
INIS
- Country of Publication
- United States
- Country of Input or Organization
- United States
- INIS RN
- 13683231
- Subject category
- S38: RADIATION CHEMISTRY, RADIOCHEMISTRY AND NUCLEAR CHEMISTRY;
- Resource subtype / Literary indicator
- Numerical Data
- Descriptors DEI
- ACTINIDE COMPOUNDS; CARBON MONOXIDE; CHEMICAL REACTIONS; EXPERIMENTAL DATA; ORGANOMETALLIC COMPOUNDS; REACTION KINETICS
- Descriptors DEC
- CARBON COMPOUNDS; CARBON OXIDES; CHALCOGENIDES; DATA; INFORMATION; KINETICS; NUMERICAL DATA; ORGANIC COMPOUNDS; OXIDES; OXYGEN COMPOUNDS