Published September 11, 2006 | Version v1
Journal article

Electrochemical behavior of adrenaline at the carbon atom wire modified electrode

  • 1. Chemistry Department, Nanjing Normal University, Jiangsu Engineering Research Center for Bio-medical Function Materials, 122 NingHai Road, Nanjing, JiangSu 210097 (China)

Description

Electrochemical behavior of adrenaline at an electrode modified by carbon atom wires (CAWs), a new material, was investigated by cyclic voltammetry combined with UV-vis spectrometry, and forced convection method. As to the electrochemical response of redox of adrenaline/adrenalinequinone couple in 0.50 M H2SO4, at a nitric acid treated CAW modified electrode, the anodic and cathodic peak potentials E pa and E pc shifted by 87 mV negatively and 139 mV in the positive direction, respectively, and standard heterogeneous rate constant k 0 increased by 16 times compared to the corresponding bare electrode, indicating the extraordinary activity of CAWs in electrocatalysis for the process

Additional details

Identifiers

DOI
10.1016/j.chemphys.2006.05.004;
PII
S0301-0104(06)00272-2;

Publishing Information

Journal Title
Chemical Physics
Journal Volume
327
Journal Issue
2-3
Journal Page Range
p. 319-326
ISSN
0301-0104
CODEN
CMPHC2

Optional Information

Copyright
Copyright (c) 2006 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved.