Published September 11, 2006
| Version v1
Journal article
Electrochemical behavior of adrenaline at the carbon atom wire modified electrode
- 1. Chemistry Department, Nanjing Normal University, Jiangsu Engineering Research Center for Bio-medical Function Materials, 122 NingHai Road, Nanjing, JiangSu 210097 (China)
Description
Electrochemical behavior of adrenaline at an electrode modified by carbon atom wires (CAWs), a new material, was investigated by cyclic voltammetry combined with UV-vis spectrometry, and forced convection method. As to the electrochemical response of redox of adrenaline/adrenalinequinone couple in 0.50 M H2SO4, at a nitric acid treated CAW modified electrode, the anodic and cathodic peak potentials E pa and E pc shifted by 87 mV negatively and 139 mV in the positive direction, respectively, and standard heterogeneous rate constant k 0 increased by 16 times compared to the corresponding bare electrode, indicating the extraordinary activity of CAWs in electrocatalysis for the process
Additional details
Identifiers
- DOI
- 10.1016/j.chemphys.2006.05.004;
- PII
- S0301-0104(06)00272-2;
Publishing Information
- Journal Title
- Chemical Physics
- Journal Volume
- 327
- Journal Issue
- 2-3
- Journal Page Range
- p. 319-326
- ISSN
- 0301-0104
- CODEN
- CMPHC2
INIS
- Country of Publication
- Netherlands
- Country of Input or Organization
- International Atomic Energy Agency (IAEA)
- INIS RN
- 39096758
- Subject category
- S74: ATOMIC AND MOLECULAR PHYSICS;
- Descriptors DEI
- ADRENALINE; CARBON; ELECTROCHEMISTRY; ELECTRODES; FORCED CONVECTION; NITRIC ACID; REACTION KINETICS; SPECTROSCOPY; SULFURIC ACID; VOLTAMETRY
- Descriptors DEC
- ADRENAL HORMONES; AUTONOMIC NERVOUS SYSTEM AGENTS; CARDIOTONICS; CARDIOVASCULAR AGENTS; CHEMISTRY; CONVECTION; DRUGS; ELEMENTS; ENERGY TRANSFER; HEAT TRANSFER; HORMONES; HYDROGEN COMPOUNDS; INORGANIC ACIDS; INORGANIC COMPOUNDS; KINETICS; MASS TRANSFER; NEUROREGULATORS; NITROGEN COMPOUNDS; NONMETALS; OXYGEN COMPOUNDS; SULFUR COMPOUNDS; SYMPATHOMIMETICS
Optional Information
- Copyright
- Copyright (c) 2006 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved.