Decomposition of high-pressure (400 kPa) SF6-CO2, SF6-CO, SF6-N2-CO2 and SF6-N2-CO mixtures under negative dc coronas

Sulfur hexafluoride, SF6, is successfully employed by the electric power industry for gas insulated equipment. However, it is a potent greenhouse gas and mixtures of SF6 with more friendly environmental gases have recently been proposed. It was demonstrated that SF6 mixed with N2 and/or CO2 could be a good substitute for some insulation applications such as gas-insulated transmission lines (GILs). Considering the possible occurrence of corona discharges in GILs, the decomposition of these gas mixtures under such stress must be studied. In this paper, the chemical stability under negative corona of SF6 and SF6-N2 (10 : 90) or (5 : 95) mixtures was investigated at 400 kPa on adding percentages of CO2 up to 80%. The corona discharges were generated at 230C in a 340 cm3 experimental cell between a stainless steel point connected to a high voltage source and a plane of aluminium. The gaseous decomposition products were assayed by gas chromatography at the end of each run carried out over a range of transported charges covering 8-17 C. The presence of CO2 in SF6 and SF6-N2 mixtures submitted to negative coronas leads to: 1. a considerable increase in the formation of the major compound group (SOF4+SO2F2),; 2. formation of similar large quantities of COF2,; 3. abundant production of CO with diluted SF6 in nitrogen,; 4. decreased formation of S2F10