Published June 2005 | Version v1
Journal article Metadata-only

Synthesis and study of ammonium-containing germanium and titanium fluoride complexes (NH4)4Li2(AF6)3 and NH4NaAF6 (A = Ge, Ti)

Creators

  • 1. DVO RAN, Inst. Khimii, Vladivostok (Russian Federation)

Description

Ammonium-containing germanium and titanium fluoride complexes (NH4)4Li2(AF6)3 and NH4NaAF6 (A = Ge, Ti) with a hetero atomic cationic sublattice have been synthesized for the first time and studied by the X-ray powder diffraction method. The unit cell parameters of these compounds are determined. The IR absorption spectra of the synthesized fluoride complexes recorded in the range 4000-350 cm-1 are interpreted

Abstract (Russian)

Впервые синтезированы и рентгенографически исследованы аммонийсодержащие фторокомплексы германия и титана состава (NH4)4Li2(AF6)3 и NH4NaAF6 (А = Ge, Ti) с гетероатомной катионной подрешеткой. Определены параметры элементарных ячеек этих соединений. Измерены и интерпретированы ИК-спектры поглощения синтезированных фторокомплексов в области 4000-350 см-1

Additional details

Additional titles

Original title (Russian)
Синтез и характеристика аммонийсодержащих фторокомплексов германия и титана состава (NH

Publishing Information

Journal Title
Zhurnal Neorganicheskoj Khimii
Journal Volume
50
Journal Issue
6
Journal Page Range
p. 935-938
ISSN
0044-457X
CODEN
ZNOKAQ

INIS

Country of Publication
Russian Federation
Country of Input or Organization
Russian Federation
INIS RN
36100242
Subject category
S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
Descriptors DEI
AMMONIUM COMPOUNDS; CHEMICAL COMPOSITION; CHEMICAL PREPARATION; DENSITY; FLUORIDES; GERMANIUM COMPLEXES; INFRARED SPECTRA; LATTICE PARAMETERS; LITHIUM COMPOUNDS; MONOCLINIC LATTICES; TITANIUM COMPLEXES
Descriptors DEC
ALKALI METAL COMPOUNDS; COMPLEXES; CRYSTAL LATTICES; CRYSTAL STRUCTURE; FLUORINE COMPOUNDS; HALIDES; HALOGEN COMPOUNDS; PHYSICAL PROPERTIES; SPECTRA; SYNTHESIS; TRANSITION ELEMENT COMPLEXES

Optional Information

Notes
11 refs., 4 tabs.