Published September 15, 1981 | Version v1
Journal article

Correlated prolate--spheroidal wave functions for the excited states /sup 1,3/Σ/sub g/+(1sg-italic, 2sg-italic) of H2 and He22+

  • 1. Laboratoire d'Astrophysique Fondamentale, Observatoire de Meudon, F 92190 Meudon, France

Description

The total energy of the excited states /sup 1,3/Σ/sub g/+(1sg, 2sg) H2 and He22+ has been calculated for several values of the internuclear distance from a one-parameter correlated prolate--spheroidal wave function. Such diabatic results are seen to be in fairly good agreement with the best adiabatic ones outside the avoided-crossing regions

Additional details

Publishing Information

Journal Title
J. Chem. Phys.
Journal Volume
75
Journal Issue
6
Series
J. Chem. Phys.
Journal Page Range
2932-2934
ISSN
0021-9606

INIS

Country of Publication
United States
Country of Input or Organization
United States
INIS RN
13646040
Subject category
S74: ATOMIC AND MOLECULAR PHYSICS;
Descriptors DEI
ELECTRON CORRELATION; ELECTRONIC STRUCTURE; EXCITED STATES; HELIUM; HYDROGEN; MOLECULAR IONS; WAVE FUNCTIONS
Descriptors DEC
CHARGED PARTICLES; CORRELATIONS; ELEMENTS; ENERGY LEVELS; FUNCTIONS; IONS; NONMETALS; RARE GASES