Published September 1986 | Version v1
Journal article Metadata-only

Catalysis of reductive hydrolysis of molecular deuterium by a rhodium complex: D2 + 2e- + 2H+→ 2HD (Rh)

Creators

  • 1. Branch of the Institute of Chemical Physics, Academy of Sciences of the USSR, Chernogolovka

Description

The reductive hydrolysis of molecular deuterium D2 + 2H+ + 2e- → 2HD proceeding (Rh) in the presence of a complex of rhodium with diphenyl-micro-sylfophenylphosphine is reported. Divalent vanadium sulfate was used as the reducing agent. A possible mechanism is discussed

Additional details

Publishing Information

Journal Title
Kinet. Catal. (Engl. Transl.)
Journal Volume
27
Journal Issue
2
Series
Kinet. Catal. (Engl. Transl.).
Journal Page Range
281-284
ISSN
0023-1584
CODEN
KICAA

INIS

Country of Publication
United States
Country of Input or Organization
United States
INIS RN
18055019
Subject category
S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
Descriptors DEI
AQUEOUS SOLUTIONS; CATALYSIS; CHEMICAL REACTION KINETICS; DEUTERIUM; HYDROLYSIS; ISOTOPIC EXCHANGE; NITROGEN; NITROGENASE; REDUCTION; RHODIUM CHLORIDES; RHODIUM COMPLEXES; VANADIUM SULFATES
Descriptors DEC
CHEMICAL REACTIONS; CHLORIDES; CHLORINE COMPOUNDS; COMPLEXES; DECOMPOSITION; DEHYDROGENASES; DISPERSIONS; ELEMENTS; ENZYMES; HALIDES; HALOGEN COMPOUNDS; HOMOGENEOUS MIXTURES; HYDROGEN ISOTOPES; ISOTOPES; KINETICS; LIGHT NUCLEI; MIXTURES; NONMETALS; NUCLEI; ODD-ODD NUCLEI; ORGANIC COMPOUNDS; OXIDOREDUCTASES; OXYGEN COMPOUNDS; REACTION KINETICS; RHODIUM COMPOUNDS; SOLUTIONS; SOLVOLYSIS; STABLE ISOTOPES; SULFATES; SULFUR COMPOUNDS; TRANSITION ELEMENT COMPLEXES; TRANSITION ELEMENT COMPOUNDS; VANADIUM COMPOUNDS

Optional Information

Notes
Cover-to-cover translation of Kinetika i Kataliz (USSR).