Published May 1975 | Version v1
Journal article Metadata-only

On reaction of lithium derivatives of o- and m-carboranes with alkoxychlorsilanes

Creators

  • 1. Vsesoyuznyj Nauchno-Issledovatel'skij Inst. Sinteza Mineral'nogo Syr'ya, Aleksandrov (USSR)

Description

Conditions of silylation of lithium derivatives o- and m-carboranes by alcoxychlorsilan, providing high output of alcoxysilylcarboron, were found. Suppositions on the mechanism of the reaction of alcoxysilylcarborons oligomerization, catalysed by basic agents were made. Alkoxysilylcarborons structures were confirmed by the infra-red spectroscopy

Additional details

Additional titles

Original title (Russian)
O reaktsii litievykh proizvodnykh o- i m-karboranov s alkoksikhlorsilanami

Publishing Information

Journal Title
Zh. Obshch. Khim.
Journal Volume
45
Journal Issue
5
Series
Zh. Obshch. Khim.
Journal Page Range
1049-1052

INIS

Country of Publication
USSR
Country of Input or Organization
USSR
INIS RN
7262546
Subject category
S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
Descriptors DEI
CHEMICAL REACTION KINETICS; CHEMICAL REACTIONS; INFRARED SPECTRA; LITHIUM COMPOUNDS; ORGANIC BORON COMPOUNDS; ORGANOMETALLIC COMPOUNDS; SILANES
Descriptors DEC
ALKALI METAL COMPOUNDS; HYDRIDES; HYDROGEN COMPOUNDS; KINETICS; ORGANIC COMPOUNDS; REACTION KINETICS; SILICON COMPOUNDS; SPECTRA

Optional Information

Notes
For English translation see the journal J. Gen. Chem. USSR.