Published September 1975 | Version v1
Journal article Metadata-only

The radiation chemistry of heteropoly electrolytes

Creators

  • 1. Democritus Nuclear Research Center, Athens (Greece). Chemistry Div.

Description

The continuous radiolysis of aqueous solutions of various characteristic heteropoly electrolytes of molybdenum and tungsten has been investigated. Oxidizing radicals such as OH radicals have no effect. On the contrary reducing species H radicals, e-(aq) and organic radicals, originating from alcohols or acids, produce the so called heteropoly blues in analogy with electrochemical and chemical reducing reagents. (orig.)

Abstract (German)

Die kontinuierliche Radiolyse von waessrigen Loesungen von verschiedenen Heteropoly-Elektrolyten des Molybdaens und Wolframs wurde untersucht. Oxydierende Radikale wie OH Radikale zeigen keinen Effekt. Im Gegensatz dazu erzeugen reduzierende Mittel wie H Radikale, e-(aq) oder organische Radikale, die aus Alkoholen oder Saeuren stammen, genauso wie elektrochemisch und chemisch reduzierende Reagenzien, sogenannte 'heteropoly-blaue' Produkte. (orig.)

Additional details

Identifiers

DOI
10.1524/zpch.1975.97.5_6.313;

Publishing Information

Journal Title
Zeitschrift für Physikalische Chemie
Journal Volume
97
Journal Issue
5_6
Series
Z. Phys. Chem. (Frankfurt).
Journal Page Range
313-320
ISSN
0942-9352

INIS

Country of Publication
Germany
Country of Input or Organization
Germany
INIS RN
7262645
Subject category
S38: RADIATION CHEMISTRY, RADIOCHEMISTRY AND NUCLEAR CHEMISTRY; S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
Descriptors DEI
AQUEOUS SOLUTIONS; ELECTROLYTES; HETEROPOLYANIONS; IRRADIATION; MOLYBDENUM COMPOUNDS; RADIATION CHEMISTRY; RADICALS; RADIOLYSIS; TIME DEPENDENCE; TUNGSTEN COMPOUNDS
Descriptors DEC
ANIONS; CHARGED PARTICLES; CHEMICAL RADIATION EFFECTS; CHEMICAL REACTIONS; CHEMISTRY; COMPLEXES; DECOMPOSITION; DISPERSIONS; HOMOGENEOUS MIXTURES; IONS; MIXTURES; RADIATION EFFECTS; SOLUTIONS; TRANSITION ELEMENT COMPOUNDS

Optional Information

Notes
1 fig.; 1 tab.; 14 refs.; Updated automatically by Metadata and Full-Text Enrichment Agent