Published August 1, 1983
| Version v1
Journal article
<110> oriented FCl- molecule--ion in KF
- 1. Argonne National Laboratory, Argonne Illinois 60439
Description
The heteronuclear diatomic molecule--ion FC1- with its molecular axis oriented along a crystal face diagonal, i.e., FC1- <110>, has been produced by ionizing radiation in single crystal KF doped with PbCl2 and KC1. Evidence to support this species identification as well as its orientation relative to the lattice is obtained from anisotropic optical absorption spectral measurements as well as from electron spin resonance (ESR) absorption spectra. Optical absorption spectral data, estimates of the molecular reorientation temperature, as well as ESR absorption spectral parameters are given for the FCl- <110>. A qualitative explanation of the differences of the optical and ESR parameters of FCl- <111> and FCl- <110> is discussed
Additional details
Publishing Information
- Journal Title
- J. Chem. Phys.
- Journal Volume
- 79
- Journal Issue
- 3
- Series
- J. Chem. Phys.
- Journal Page Range
- 1408-1415
- ISSN
- 0021-9606
INIS
- Country of Publication
- United States
- Country of Input or Organization
- United States
- INIS RN
- 14791543
- Subject category
- S38: RADIATION CHEMISTRY, RADIOCHEMISTRY AND NUCLEAR CHEMISTRY;
- Descriptors DEI
- ABSORPTION SPECTRA; CHLORINE FLUORIDES; DOPED MATERIALS; ELECTRON SPIN RESONANCE; IONIZING RADIATIONS; LEAD CHLORIDES; MOLECULAR IONS; MONOCRYSTALS; ORIENTATION; POTASSIUM CHLORIDES; POTASSIUM FLUORIDES; RADIOLYSIS
- Descriptors DEC
- ALKALI METAL COMPOUNDS; CHARGED PARTICLES; CHEMICAL RADIATION EFFECTS; CHEMICAL REACTIONS; CHLORIDES; CHLORINE COMPOUNDS; CRYSTALS; DECOMPOSITION; FLUORIDES; FLUORINE COMPOUNDS; HALIDES; HALOGEN COMPOUNDS; IONS; LEAD COMPOUNDS; MAGNETIC RESONANCE; MATERIALS; POTASSIUM COMPOUNDS; RADIATION EFFECTS; RADIATIONS; RESONANCE; SPECTRA