Published October 1979
| Version v1
Journal article
Effect of geometry changes in vibrational promoting modes on the rate constants of radiationless transitions
- 1. Polska Akademia Nauk, Warsaw. Inst. Fizyki
Description
The influence of changes in geometry of promoting vibrational modes (due to transitions between electronic states) on the rate constants for radiationless transitions in molecular systems has been analysed. It has been demonstrated that in many-promoting-modes model systems, effects due to interferences between different participating modes can greatly modify the magnitudes of rate constants for radiationless transitions as well as the magnitude of the isotope (deuterium) effect. (author)
Additional details
Publishing Information
- Journal Title
- Acta Phys. Pol., Ser. A
- Journal Volume
- 56
- Journal Issue
- 4
- Series
- Acta Phys. Pol., Ser. A.
- Journal Page Range
- 535-541
- ISSN
- 0587-4246
INIS
- Country of Publication
- Poland
- Country of Input or Organization
- Poland
- INIS RN
- 12576226
- Subject category
- S74: ATOMIC AND MOLECULAR PHYSICS;
- Descriptors DEI
- CONFIGURATION INTERACTION; ELECTRONIC STRUCTURE; INTERFERENCE; ISOTOPE EFFECTS; MOLECULAR STRUCTURE; OSCILLATION MODES; RADIATIONLESS DECAY
- Descriptors DEC
- DE-EXCITATION; ENERGY TRANSFER; ENERGY-LEVEL TRANSITIONS