Published June 14, 2011 | Version v1
Journal article Metadata-only

An unsupported uranium-rhenium complex prepared by alkane elimination

Creators

  • 1. School of Chemistry, University of Nottingham (United Kingdom)

Description

An unsupported uranium-rhenium bond has been prepared by alkane elimination by treatment of a cyclometallated alkyl uranium triamidoamine complex with rhenocene hydride. DFT analysis reveals σ and π combinations in the U-Re bond, but the rhenium contributions dominate and an atoms-in-molecules analysis reveals a closed-shell, predominantly ionic uranium-rhenium interaction. (Copyright copyright 2011 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim)

Availability note (English)

Available from: http://dx.doi.org/10.1002/chem.201100682

Additional details

Identifiers

DOI
10.1002/chem.201100682;

Publishing Information

Journal Title
Chemistry (Weinheim)
Journal Volume
17
Journal Issue
25
Journal Page Range
p. 6909-6912
ISSN
0947-6539
CODEN
CEUJED

INIS

Country of Publication
Germany
Country of Input or Organization
Germany
INIS RN
48046091
Subject category
S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
Descriptors DEI
ALKANES; CHEMICAL BONDS; DENSITY FUNCTIONAL METHOD; ORGANOMETALLIC COMPOUNDS; RHENIUM COMPLEXES; SYNTHESIS; URANIUM COMPLEXES
Descriptors DEC
ACTINIDE COMPLEXES; CALCULATION METHODS; COMPLEXES; HYDROCARBONS; ORGANIC COMPOUNDS; TRANSITION ELEMENT COMPLEXES; VARIATIONAL METHODS

Optional Information

Notes
With 6 figs., 1 tab., 50 refs.