Transport and magnetic properties of Sr2FeMoxW1-xO6

We have investigated transport and magnetic properties of a series of double-perovskite alloys in the system Sr2FeMoxW1-xO6. These compounds exhibit a metal-insulator transition as a function of doping, x. The compounds with x in the range 1.0≥x≥0.3 show metallic behaviour in the resistivity while compounds with x in the range 0.2≥x≥0 are insulating. All compounds with 1.0≥x≥0.2 are ferrimagnetic, while Sr2FeWO6 (x 0) is antiferromagnetic. The magnetization (M) is shown to increase slowly with decreasing x in the range 1.0≥x≥0.3 due to an enhanced crystallographic ordering; however, M decreases rapidly with decreasing x thereafter (x<0.3), probably due to composition fluctuations near the critical concentration, xc. Our data suggest primarily Fe3+-(Mo, W)5+ ordering for x≥0.3, while compositions with smaller x possibly contain both Fe3+ and Fe2+ species inhomogeneously due to the presence of the W6+ state. All samples with x≥0.3 show a significant amount of negative magnetoresistance, as has been observed earlier for Sr2FeMoO6 (x=1.0). (author)