Published February 15, 1989 | Version v1
Journal article

Tetraamminebis[tetraiodothallate(III)]copper(II)

Creators

  • 1. Koeln Univ. (Germany, F.R.). Inst. fuer Anorganische Chemie

Description

[Cu(TlI4)2(NH3)4], Mr=1555.671, monoclinic, P21/n, a=7.699(2), b=13.997(4), c=11.174(2) A, β=95.39(2)0, V=1197.9 A3, Z=2, Dx=4.313 Mg m-3, λ(Mo Kα)=0.71069 A, μ=24.639 mm-1, F(000)=2620, T=299 K, R=0.035 for 1658 reflections [vertical strokeF0vertical stroke≥3σ(F0)]. The structure consists of planar Cu(NH3)42+ complexes further coordinated by I atoms of slightly distorted TlI4- tetrahedra making a stretched octahedron. Bond lengths and angles are in the expected range. (orig.)

Additional details

Additional titles

Original title (German)
Tetraamminbis[tetraiodothallat(III)]kupfer(II)

Publishing Information

Journal Title
Acta Crystallographica, Section C
Journal Volume
45
Journal Issue
2
Series
Acta Crystallogr., Sect. C.
Journal Page Range
180-182
ISSN
0108-2701
CODEN
ACSCE