Establishing a Database of High Temperature Salt Properties for Nuclear Applications

The Fluoride-Salt-Cooled High-Temperature Reactor (FHR) is a new reactor concept employing a high temperature liquid salt fluoride coolant. The thermophysical property data for candidate salt coolants is very limited. The uncertainties of these properties are quite high and not well documented. For researchers exploring reactor designs such as the FHR, a database of high temperature liquid salts for nuclear applications is being established. Researchers can use the database, which will be updated with new experimental data, to find thermophysical properties and associated uncertainties for salt coolants to use in their analyses. This paper serves as an introduction of the database and highlights the main three coolants in the database that are considered for use in the FHR design. The salts considered for the Fluoride-Salt-Cooled High- Temperature Reactor (FHR) include LiF-BeF₂ (flibe) and NaFZrF₄ (nafzirf) as potential primary loop coolants and LiF-NaFKF (flinak) as a secondary loop coolant. Flibe is the primary candidate for the primary loop coolant. It has the lowest neutron cross section, is chemically stable with low corrosion rates in high-nickel alloy systems, and is weakly radioactive with the primary activation product tritium resulting in very low radiation levels in the primary loop. Flibe does have some disadvantages, which include toxicity of beryllium and the need to enrich lithium to at least 99.995% Li-7 to maintain a low nuclear cross section. For design analysis, the baseline salt used is nafzirf because it has less attractive neutronic and thermophysical properties. The benefits of nafzirf over flibe including no direct tritium production and lower cost. By designing a reactor to operate using nafzirf, it is assumed that the reactor will operate better using flibe as the coolant. Thus, one can consider the coolants flibe and nafzirf to be bounding primary salt coolants for reactor design. (authors)