Published 2015 | Version v1
Journal article

Molecular design of Calix[4]arene derivatives for uranyl ion extraction from aqueous media

Creators

  • 1. Hacettepe University Department of Chemistry, Organic Chemistry Section, Ankara (Turkey)

Description

Uranyl ion extraction is an important part of nuclear waste reprocessing. Use of organic ligands having chelating property with uranyl ions is a promising tool in this area, because of the possibility to improve the selectivity and the affinity of the ligands towards uranyl ions. In this study, Calix[4]arene derivatives containing B, Al, C, Si, N, P, O and S elements in bridging positions were designed and their chelating energetics with uranyl cation are calculated by means of DFT methods.

Availability note (English)

Available from: http://www.bgns-transactions.org/uploads/journal/20-2/vol.20-2_12.pdf

Additional details

Publishing Information

Journal Title
BgNS Transactions
Journal Volume
20
Journal Issue
2
Journal Page Range
p. 137-139
ISSN
1310-8727

Conference

Title
Bulgarian Nuclear Society Annual Conference on Nuclear power for the people
Dates
2-5 Sep 2015
Place
Sozopol (Bulgaria)

INIS

Country of Publication
Bulgaria
Country of Input or Organization
Bulgaria
INIS RN
47076556
Subject category
S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
Resource subtype / Literary indicator
Conference
Descriptors DEI
BINDING ENERGY; CALIXARENES; CHELATING AGENTS; EXTRACTION; LIGANDS; RADIOACTIVE WASTES; URANYL COMPLEXES
Descriptors DEC
ACTINIDE COMPLEXES; AROMATICS; COMPLEXES; CONDENSED AROMATICS; ENERGY; MATERIALS; ORGANIC COMPOUNDS; RADIOACTIVE MATERIALS; SEPARATION PROCESSES; URANIUM COMPLEXES; WASTES

Optional Information

Notes
2 figs., 2 tabs., 13 refs.; This record replaces 47071027