Published February 1985
| Version v1
Journal article
Basicity of carbonyl metal complexes
Creators
- 1. AN SSSR, Moscow. Inst. Ehlementoorganicheskikh Soedinenij
Description
By the method of IR-spectroscopy in the field of CO and NO group oscillation frequencies the reactions of eta5-cyclopentadienyl and eta6-arene complexes of Cr, Mo, W, Mn, Re with AlBr3 and GaCl3 aprotic acids are studied. It is shown that C5H5Mo(CO)2(NO) reacts with AlBr3 in benzene producing mostly oxygen adducts of CO(or NO) groups. The C5H5Re(CO)2 PPh3 (where PPh3 is trifenylphosphine), as well as C6H6W(CO)3, Me3C6H3Mo (CO)3 and Me3H3W(CO)3 react with AlBr3 and GaCl3 in dichloroethane with formation of metal atom adducts
Additional details
Additional titles
- Subtitle (English)
- Communication 18. Interaction of cyclopentadienyl and arene eta-complexes of 6 and 7 group metals with aprotic acids AlBr_3 and GaCl_3
- Original title (Russian)
- Основност' карбонильных комплексов металлов
- Original subtitle (Russian)
- Soobshchenie 18. Vzaimodejstvie tsiklopentadienil'nykh i arenovykh eta-kompleksov metallov 6 i 7 grupp s aprotonnymi kislotami AlBr_3 i GaCl_3.
- Augmented title (English)
- Metals: Cr, Mo, W, Mn, Re
Publishing Information
- Journal Title
- Izv. Akad. Nauk SSSR, Ser. Khim.
- Journal Issue
- no.2
- Series
- Izv. Akad. Nauk SSSR, Ser. Khim.
- ISSN
- 0002-3353
INIS
- Country of Publication
- Russian Federation
- Country of Input or Organization
- USSR
- INIS RN
- 16070255
- Subject category
- S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
- Descriptors DEI
- ABSORPTION SPECTRA; ADDUCTS; ALUMINIUM BROMIDES; BENZENE; CARBONYLS; CHEMICAL BONDS; CHEMICAL REACTIONS; CYCLOALKENES; DIENES; GALLIUM CHLORIDES; INFRARED SPECTRA; MOLYBDENUM COMPLEXES; ORGANIC CHLORINE COMPOUNDS; RHENIUM COMPLEXES; TUNGSTEN COMPLEXES
- Descriptors DEC
- ALKENES; ALUMINIUM COMPOUNDS; AROMATICS; BROMIDES; BROMINE COMPOUNDS; CHLORIDES; CHLORINE COMPOUNDS; COMPLEXES; GALLIUM COMPOUNDS; HALIDES; HALOGEN COMPOUNDS; HYDROCARBONS; ORGANIC COMPOUNDS; ORGANIC HALOGEN COMPOUNDS; POLYENES; SPECTRA; TRANSITION ELEMENT COMPLEXES
Optional Information
- Notes
- For English translation see the journal Bulletin of the Academy of Sciences USSR, Division of Chemical Science (USA).