Published October 5, 1988
| Version v1
Journal article
Synthesis, structure, electrochemistry, and photophysics of methyl-substituted phenylpyridine ortho-metalated iridium(III) complexes
Description
Synthetic, structural, photophysical, and electrochemical characterizations of ortho-metalated [Ir(NC)2Cl]2 dimeric and [Ir(NC)2NN]Cl monomeric complexes, where NC = 2(p-tolyl)pyridine (ptpy) or 3-methyl-2-phenylpyridine (mppy) and NN = 2,2'-bipyridine (bpy) are described. Structural characterizations by 1H and 13C nuclear magnetic resonance (NMR) indicate the presence of symmetry elements in these complexes. The ultraviolet-visible absorption properties of these complexes are reported. The results of voltametric measurements of these complexes are included. 55 references, 10 figures, 6 tables
Additional details
Publishing Information
- Journal Title
- Inorganic Chemistry
- Journal Volume
- 27
- Journal Issue
- 20
- Series
- Inorg. Chem.
- Journal Page Range
- 3464-3471
- ISSN
- 0020-1669
- CODEN
- INOCA
INIS
- Country of Publication
- United States
- Country of Input or Organization
- United States
- INIS RN
- 20055209
- Subject category
- S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY; S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
- Resource subtype / Literary indicator
- Numerical Data
- Descriptors DEI
- BIPYRIDINES; CARBON 13; EXPERIMENTAL DATA; HETEROCYCLIC COMPOUNDS; IRIDIUM COMPLEXES; MOLECULAR STRUCTURE; NMR SPECTRA; PROTONS; PYRIDINES; SYNTHESIS; TOLYL RADICALS
- Descriptors DEC
- ARYL RADICALS; AZINES; BARYONS; CARBON ISOTOPES; CATIONS; CHARGED PARTICLES; COMPLEXES; DATA; ELEMENTARY PARTICLES; EVEN-ODD NUCLEI; FERMIONS; HADRONS; HYDROGEN IONS; HYDROGEN IONS 1 PLUS; INFORMATION; IONS; ISOTOPES; LIGHT NUCLEI; NUCLEI; NUCLEONS; NUMERICAL DATA; ORGANIC COMPOUNDS; ORGANIC NITROGEN COMPOUNDS; RADICALS; SPECTRA; STABLE ISOTOPES; TRANSITION ELEMENT COMPLEXES