Measurement of actinide concentration in solution samples from the NUCEF reprocessing facility by X-ray and low energy gamma-ray spectroscopy

X-ray and low-energy gamma-ray spectroscopy has been used to measure actinide concentration within the backend nuclear fuel reprocessing research facility at NUCEF. Research on advanced reprocessing techniques at NUCEF is based on the PARC refinement of the PUREX process which aims to recover Am and Cm from the highly active waste stream and to control and partition Np and Tc. It is hoped that the PARC process will mitigate the environmental impact of the wastes and improve the economy of reprocessing. The main actinides for which assay is required are U, Pu, Np and Am and knowledge of these concentrations will enable the following to be determined: i.) evaluation of the distribution of actinides throughout the reprocessing facility ii.) verification of the simulated actinide distribution from chemical kinetic simulations of the PARC process and iii.) assurance of safety and control over migrant radioactive species. The research presented here shows that passive measurement of x-rays and low-energy gamma-rays from solution samples provides an accurate and non-destructive means for assaying the concentration. The measurement technique is based on the use of the characteristic low energy gamma-rays and internal conversion x-ray emission from actinides (11 keV to 22 keV). The x-ray emission is a few orders of magnitude more intense than the characteristic gamma-ray emission and can be easily detected from solutions. The experimental system described here can be used for solution monitoring to a minimum concentration of typically 10-6 M for Pu, 10-10 M for Am and 10-6 M for Np. (author)