Published October 1, 2014 | Version v1
Journal article Metadata-only

Advantages of N2 and Ar as reaction gases for measurement of multiple Se isotopes using inductively coupled plasma-mass spectrometry with a collision/reaction cell

Creators

  • 1. Trace Element Research Laboratory, School of Earth Sciences, The Ohio State University, 125 S. Oval Mall, Columbus, OH 43210 (United States)
  • 2. Department of Chemistry, The Ohio State University, 120 18th Avenue, Columbus, OH 43210 (United States)

Description

Thirteen collision/reaction gases (CH4, O2, H2, CH3F, C2H6, N2O, NH3, SF6, Xe, Ne, N2, CO and Ar) were investigated to reduce the ArAr+, Ar2H+, Ar2H2+, SeH+, BrH+ and ArCl+ overlaps on Se+ isotopes. N2 and Ar had particular advantages for the measurement of multiple Se isotopes compared to the other gases. Experiments using CH4 and CD4 determined that H-atom transfer from CH4 to Se+ resulted in the formation of SeH+

Availability note (English)

Available from http://dx.doi.org/10.1016/j.sab.2014.08.015

Additional details

Identifiers

DOI
10.1016/j.sab.2014.08.015;
PII
S0584-8547(14)00190-6;

Publishing Information

Journal Title
Spectrochimica Acta. Part B, Atomic Spectroscopy
Journal Volume
100
Journal Page Range
p. 197-210
ISSN
0584-8547
CODEN
SAASBH

INIS

Country of Publication
Netherlands
Country of Input or Organization
International Atomic Energy Agency (IAEA)
INIS RN
47009046
Subject category
S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
Descriptors DEI
AMMONIA; ARGON; CARBON MONOXIDE; COMPARATIVE EVALUATIONS; DISSOCIATION; ETHANE; GASES; HYDROGEN; ICP MASS SPECTROSCOPY; METHANE; METHYL FLUORIDE; MOLECULAR IONS; NITROGEN; NITROUS OXIDE; REDUCTION; SELENIUM IONS; SELENIUM ISOTOPES; SULFUR FLUORIDES
Descriptors DEC
ALKANES; CARBON COMPOUNDS; CARBON OXIDES; CHALCOGENIDES; CHARGED PARTICLES; CHEMICAL REACTIONS; ELEMENTS; EVALUATION; FLUIDS; FLUORIDES; FLUORINATED ALIPHATIC HYDROCARBONS; FLUORINE COMPOUNDS; GASES; HALIDES; HALOGEN COMPOUNDS; HALOGENATED ALIPHATIC HYDROCARBONS; HYDRIDES; HYDROCARBONS; HYDROGEN COMPOUNDS; IONS; ISOTOPES; MASS SPECTROSCOPY; NITROGEN COMPOUNDS; NITROGEN HYDRIDES; NITROGEN OXIDES; NONMETALS; ORGANIC COMPOUNDS; ORGANIC FLUORINE COMPOUNDS; ORGANIC HALOGEN COMPOUNDS; OXIDES; OXYGEN COMPOUNDS; RARE GASES; SPECTROSCOPY; SULFUR COMPOUNDS; SULFUR HALIDES

Optional Information

Copyright
Copyright (c) 2014 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved.