Published 2016
| Version v1
Report
The local structure of Sm and Tb in Sm1-xTbxPO4
- 1. Helmholtz-Zentrum Dresden-Rossendorf e.V., Dresden (Germany). Div. Molecular Structures
- 2. Forschungszentrum Juelich GmbH (Germany). Inst. of Energy and Climate Research. IEK-6 Nuclear Waste Management and Reactor Safety
Description
Among the phosphates considered as waste forms for long-lived radionuclides, monazite stands out because of its low solubility, slow dissolution rate and high chemical flexibility to incorporate actinide elements such as Am and Cm. EXAFS was carried out to evaluate the local structure of the Sm1-xTbxPO4 solidsolution between the Sm endmember with monazite and the Tb endmember with xenotime structure.
Additional details
Publishing Information
- Imprint Title
- Annual report 2015. Institute of Resource Ecology
- Imprint Pagination
- 102 p.
- Journal Page Range
- p. 14
- ISSN
- 2191-8708
- Report number
- HZDR--067
INIS
- Country of Publication
- Germany
- Country of Input or Organization
- Germany
- INIS RN
- 48031780
- Subject category
- S12: MANAGEMENT OF RADIOACTIVE WASTES, AND NON-RADIOACTIVE WASTES FROM NUCLEAR FACILITIES;
- Descriptors DEI
- BOND LENGTHS; MONAZITES; RADIOISOTOPES; SAMARIUM PHOSPHATES; TERBIUM PHOSPHATES; WASTE FORMS; XENOTIME; X-RAY SPECTRA
- Descriptors DEC
- DIMENSIONS; ISOTOPES; LENGTH; MATERIALS; MINERALS; OXYGEN COMPOUNDS; PHOSPHATE MINERALS; PHOSPHATES; PHOSPHORUS COMPOUNDS; RADIOACTIVE MATERIALS; RADIOACTIVE MINERALS; RADIOACTIVE WASTES; RARE EARTH COMPOUNDS; SAMARIUM COMPOUNDS; SPECTRA; TERBIUM COMPOUNDS; THORIUM MINERALS; WASTES