Published February 15, 2006
| Version v1
Journal article
In situ STM study of underpotential deposition of bismuth on Au(110) in perchloric acid solution
- 1. Department of Applied Chemistry, Graduate School of Engineering, Tohoku University, 6-6-04 Aoba, Sendai 980-8579 (Japan)
- 2. NICHe, Tohoku University, 6-6-10 Aoba, Sendai 980-8579 (Japan)
- 3. Department of Applied Chemistry, Graduate School of Engineering, Tohoku University, 6-6-04 Aoba, Sendai 980-8579 (Japan) and CREST, JST, 4-1-8 Kawaguchi, Saitama 332-0012 (Japan)
Description
The underpotential deposition (UPD) of Bi on Au(110) was investigated in HClO4 solution using in situ scanning tunneling microscopy. The UPD of Bi occurred in three steps. A 3011 structure, in which Bi atoms formed dimers, was found for the first UPD adlayer. A (1x1) image was obtained by STM at the second UPD peak. For the third UPD peak, Bi atoms formed an incommensurate adlayer, and stripes of Bi were observed on terraces. After the third UPD, a structural reconstruction caused by adsorbed Bi was observed
Additional details
Identifiers
- DOI
- 10.1016/j.electacta.2005.01.067;
- PII
- S0013-4686(05)00866-2;
Publishing Information
- Journal Title
- Electrochimica Acta
- Journal Volume
- 51
- Journal Issue
- 11
- Journal Page Range
- p. 2327-2332
- ISSN
- 0013-4686
- CODEN
- ELCAAV
Conference
- Title
- International conference on electrode processes
- Dates
- 15-18 Sep 2004
- Place
- Szczyrk (Poland)
INIS
- Country of Publication
- United Kingdom
- Country of Input or Organization
- International Atomic Energy Agency (IAEA)
- INIS RN
- 38016228
- Subject category
- S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
- Resource subtype / Literary indicator
- Conference
- Descriptors DEI
- BISMUTH COMPOUNDS; DEPOSITION; GOLD COMPOUNDS; PERCHLORIC ACID; SCANNING TUNNELING MICROSCOPY; SOLUTIONS
- Descriptors DEC
- CHLORINE COMPOUNDS; DISPERSIONS; HALOGEN COMPOUNDS; HOMOGENEOUS MIXTURES; HYDROGEN COMPOUNDS; INORGANIC ACIDS; INORGANIC COMPOUNDS; MICROSCOPY; MIXTURES; OXYGEN COMPOUNDS; TRANSITION ELEMENT COMPOUNDS
Optional Information
- Copyright
- Copyright (c) 2005 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved.