Published January 15, 1991
| Version v1
Journal article
Structure of (μ-I)2Os2(CO)6I2
Creators
- 1. Ohio State Univ., Columbus (USA). Dept. of Chemistry
Description
Hexacarbonyl-1Κ3C, 2Κ3C-di-μ-iodo-1ΚI:-2ΚI-diiodo-1ΚI, 2ΚI-diosmium, [Os2(CO)6I4], monoclinic, C2/m, a=11.082(2), b=7.740(5), c=9.711(3) A, β=107.22deg, V=795.6 A3, Z=2, Dx=4.408 g cm-3, Mr=1056.08, F(000)=896, Mo Kα, λ=0.71703 A, μ=237 cm-1, room temperature, Rf=0.037 for 841 reflections. The molecular structure of the title compound consists of two (CO)3Os units bridged by two iodines. The symmetry around the Os atoms was found to be octahedral. (orig.)
Additional details
Publishing Information
- Journal Title
- Acta Crystallographica. Section C: Crystal Structure Communications
- Journal Volume
- 47
- Journal Issue
- 1
- Series
- Acta Crystallogr., Sect. C: Cryst. Struct. Comm.
- Journal Page Range
- 6-8
- ISSN
- 0108-2701
- CODEN
- ACSCE
INIS
- Country of Publication
- Denmark
- Country of Input or Organization
- Denmark
- INIS RN
- 22039605
- Subject category
- S75: CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND SUPERFLUIDITY;
- Resource subtype / Literary indicator
- Numerical Data
- Descriptors DEI
- BOND ANGLE; CARBONYLS; CRYSTAL STRUCTURE; EXPERIMENTAL DATA; INTERATOMIC DISTANCES; LATTICE PARAMETERS; MEDIUM TEMPERATURE; MOLECULAR STRUCTURE; MONOCLINIC LATTICES; MONOCRYSTALS; OSMIUM ISOTOPES; X-RAY DIFFRACTION
- Descriptors DEC
- COHERENT SCATTERING; CRYSTAL LATTICES; CRYSTALS; DATA; DIFFRACTION; DISTANCE; INFORMATION; NUMERICAL DATA; SCATTERING
Optional Information
- Contract/Grant/Project number
- Grant CHE-88-0515