Published September 26, 1986
| Version v1
Journal article
Photochemical reactions of disulphide radical anions in frozen water-salt matrix
- 1. Moskovskij Gosudarstvennyj Univ. (USSR). Khimicheskij Fakul'tet
Description
Photochemical reactions of disulfide radical anions CH3SSCH-3 induced by light with λ=436, 405 and 365 nm in a water-salt matrix of 6M LiCl at 77 K were studied. It was shown that upon excitation disulfide radical anions may enter into electron photodetachment reaction and the S-S bond is cleft. Kinetical nonequivalence of disulfide radical anions in photochemical reactions was shown to manifest itself in different mechanisms of their transformations. (author)
Additional details
Publishing Information
- Journal Title
- J. Radioanal. Nucl. Chem.
- Journal Volume
- 106
- Journal Issue
- 5
- Series
- J. Radioanal. Nucl. Chem. ;Letters.
- Journal Page Range
- 281-293
- ISSN
- 0236-5731
- CODEN
- JRNCD
INIS
- Country of Publication
- Hungary
- Country of Input or Organization
- Hungary
- INIS RN
- 18035243
- Subject category
- S38: RADIATION CHEMISTRY, RADIOCHEMISTRY AND NUCLEAR CHEMISTRY;
- Descriptors DEI
- ANIONS; DISULFIDES; ELECTRON SPIN RESONANCE; EXCITATION; LITHIUM CHLORIDES; PHOTOCHEMISTRY; PHOTOLYSIS; RADICALS; RADIOCHEMISTRY; REACTION KINETICS; TIME DEPENDENCE; WATER
- Descriptors DEC
- ALKALI METAL COMPOUNDS; CHARGED PARTICLES; CHEMICAL REACTIONS; CHEMISTRY; CHLORIDES; CHLORINE COMPOUNDS; DECOMPOSITION; ENERGY-LEVEL TRANSITIONS; HALIDES; HALOGEN COMPOUNDS; HYDROGEN COMPOUNDS; IONS; KINETICS; LITHIUM COMPOUNDS; LITHIUM HALIDES; MAGNETIC RESONANCE; ORGANIC COMPOUNDS; ORGANIC SULFUR COMPOUNDS; OXYGEN COMPOUNDS; POLAR SOLVENTS; RESONANCE; SOLVENTS
Optional Information
- Notes
- 10 refs.; 3 figs.