Published July 25, 2003 | Version v1
Journal article

Hyperfine splitting, isotope shift, and level energy of the 3S states of Li6,7

  • 1. Pacific Northwest National Laboratory, P.O. Box 999, Richland, Washington 99352 (United States)
  • 2. Gesellschaft fuer Schwerionenforschung, 64291 Darmstadt (Germany)
  • 3. Department of Physics, University of Windsor, Windsor, Ontario, N9B3P4 (Canada)

Description

We study the 2S-3S transition of Li6,7 by high-precision laser spectroscopy using two-photon Doppler-free excitation and photoionization detection. Interferometric cross referencing to metrologic Rb 3S-5D two-photon transitions allowed measurement of the transition isotope shift and hyperfine splitting in the 3S state with precision at the 30 kHz level. The results are IS=11 453.734(30) MHz, A3S(Li6)=35.263(15) MHz, and A3S(Li7)=93.106(11) MHz. Combined with recent theoretical work, the isotope shift yields a new value for the change in squared nuclear charge radii ΔR2=0.47(5) fm2. This is compared with other work and some existing discrepancies are resolved

Additional details

Publishing Information

Journal Title
Physical Review Letters
Journal Volume
91
Journal Issue
4
Journal Page Range
p. 043004-043004.4
ISSN
0031-9007
CODEN
PRLTAO

Optional Information

Notes
(c) 2003 The American Physical Society