Published 1990 | Version v1
Journal article Metadata-only

Synthesis and crystal structure of bis(2-hydroxy-1-naphthalideneanilinato)zinc (2) and -beryllium (2) complexes

Creators

  • 1. Rostovskij-na-Donu Gosudarstvennyj Univ., Rostov-na-Donu (USSR). Nauchno-Issledovatel'skij Inst. Fizicheskoj i Organicheskoj Khimii
  • 2. AN SSSR, Moscow (USSR). Inst. Obshchej i Neorganicheskoj Khimii

Description

BeL2 complex (L=O-C10H6-CH=N-Ph) has been synthesized, its X-ray diffraction analysis is conducted (R=0.085 for 1188 reflections). The crystals are monoclinic, Z=4; a=10.534, b=16.792, c=14.660 A, β=92.30, ρcalcld=1.29, F. gr. P21/n. Be atom in the complex has a distorted tetrahedral coordination. Average values of bond length and angles are: Be-O 1.58, Be-N 1.73 A, OBeO 115, NBeN 110, OBeN 104 (chelate) and 112 deg

Additional details

Additional titles

Original title (Russian)
Синтез и кристаллическая структура комплексов бис-(2-окси-1-нафталиденанилинато)цинка (2) и -бериллия (2)

Publishing Information

Journal Title
Koordinatsionnaya Khimiya
Journal Volume
16
Journal Issue
10
Series
Koord. Khim.
Journal Page Range
1360-1366
ISSN
0132-344X
CODEN
KOKHD

INIS

Country of Publication
Russian Federation
Country of Input or Organization
USSR
INIS RN
22041631
Subject category
S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
Descriptors DEI
AMINES; BERYLLIUM COMPLEXES; BOND ANGLE; BOND LENGTHS; CHEMICAL PREPARATION; CONDENSED AROMATICS; DENSITY; LATTICE PARAMETERS; MELTING POINTS; MONOCLINIC LATTICES; SPACE GROUPS
Descriptors DEC
ALKALINE EARTH METAL COMPLEXES; AROMATICS; COMPLEXES; CRYSTAL LATTICES; CRYSTAL STRUCTURE; ORGANIC COMPOUNDS; PHYSICAL PROPERTIES; SYMMETRY GROUPS; SYNTHESIS; THERMODYNAMIC PROPERTIES; TRANSITION TEMPERATURE