Benchmarking calculations with spectroscopic accuracy of level energies and wavelengths in W LVII–W LXII tungsten ions
Creators
- 1. Shanghai EBIT Lab, Key Laboratory of Nuclear Physics and Ion-beam Application, Institute of Modern Physics, Department of Nuclear Science and Technology, Fudan University, Shanghai 200433 (China)
- 2. Hebei Key Lab of Optic-electronic Information and Materials, The College of Physics Science and Technology, Hebei University, Baoding 071002 (China)
- 3. Spectroscopy, Quantum Chemistry and Atmospheric Remote Sensing (SQUARES), CP160/09, Université libre de Bruxelles, Brussels 1050 (Belgium)
- 4. Department of Materials Science and Applied Mathematics, Malmö University, Malmö, SE-20506 (Sweden)
- 5. Space Science Laboratory, University of California, Berkeley, CA 94720 (United States)
Description
Highlights: • Excitation energies and wavelengths of states of the W LVII–W LXII tungsten ions are systematically investigated. • Electron correlation, Breit interaction and QED corrections to the excitation energies are studied in detail. Atomic properties of states of the W - W ions are systematically investigated through two state-of-the-art methods, namely, the second-order many-body perturbation theory, and the multi-configuration Dirac–Hartree–Fock method combined with the relativistic configuration interaction approach. The contributions of valence-valence and core-valence electron correlations, the Breit interaction, the higher-order retardation correction beyond the Breit interaction through the transverse photon interaction, and the quantum electrodynamical corrections to the excitation energies are studied in detail. The excitation energies and wavelengths obtained with the two methods agree with each other within %. The present results achieve spectroscopic accuracy and provide a benchmark test for various applications and other theoretical calculations of W - W ions. They will assist spectroscopists in their assignment and direct identification of observed lines in complex spectra.
Availability note (English)
Available from http://dx.doi.org/10.1016/j.jqsrt.2021.107650Additional details
Identifiers
- DOI
- 10.1016/j.jqsrt.2021.107650;
- PII
- S0022407321001436;
Publishing Information
- Journal Title
- Journal of Quantitative Spectroscopy and Radiative Transfer
- Journal Volume
- 269
- Journal Page Range
- vp.
- ISSN
- 0022-4073
- CODEN
- JQSRAE
INIS
- Country of Publication
- United Kingdom
- Country of Input or Organization
- International Atomic Energy Agency (IAEA)
- INIS RN
- 54092486
- Subject category
- S74: ATOMIC AND MOLECULAR PHYSICS; S71: CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSICS;
- Descriptors DEI
- BENCHMARKS; CONFIGURATION INTERACTION; ELECTRON CORRELATION; ELECTRONS; EXCITATION; HARTREE-FOCK METHOD; MANY-BODY PROBLEM; PERTURBATION THEORY; PHOTONS; QUANTUM ELECTRODYNAMICS; RELATIVISTIC RANGE; SPECTRA; VALENCE; WAVELENGTHS
- Descriptors DEC
- APPROXIMATIONS; BOSONS; CALCULATION METHODS; CORRELATIONS; ELECTRODYNAMICS; ELEMENTARY PARTICLES; ENERGY RANGE; ENERGY-LEVEL TRANSITIONS; FERMIONS; FIELD THEORIES; LEPTONS; MASSLESS PARTICLES; QUANTUM FIELD THEORY
Optional Information
- Copyright
- Copyright (c) 2021 Elsevier Ltd. All rights reserved.