The role of two types of trellis layer for metal-insulator transition and antiferromagnetic order in the one-dimensional conductor V6O13
- 1. Institute of Physics, University of Tsukuba, Tennodai, Tsukuba 305-8571 (Japan)
- 2. Superconducting Materials Center, National Institute for Materials Science, Namiki, Tsukuba 305-0044 (Japan)
Description
V6O13 with a metal-insulator transition at Tc ≅ 150 K and an antiferromagnetic order at TN ≅ 50 K has a ddyz-type single trellis layer and a dxy-type double trellis layer, where x and y correspond to the a- and b-axis, respectively. Magnetic properties above Tc are consistent with theoretical results for a one-dimensional Hubbard model with the uniform electron concentration and a bandwidth comparable to the effective on-site Coulomb energy. Below Tc, in the light of properties of δ-phase vanadium bronzes, the spin-singlet state is considered to appear in the double trellis layer and the one-dimensional Heisenberg chain-like state is formed in the single layer, accompanied with valence order; and at TN, the antiferromagnetic order takes place in the single layer. The temperature dependence of the electrical resistivity for the one-dimensional chain above Tc is mainly due to antiferromagnetic spin fluctuations, and those for the normal directions nearly follow 1/T which is likely due to the renormalization effect of the Fermi surface by the fluctuations. The Hall coefficient above Tc is found to be roughly linear in T
Availability note (English)
Available online at http://stacks.iop.org/0953-8984/16/7863/cm4_43_025.pdf or at the Web site for the Journal of Physics. Condensed Matter (ISSN 1361-648X) http://www.iop.org/Additional details
Identifiers
- URL
- http://stacks.iop.org/0953-8984/16/7863/cm4_43_025.pdf; http://www.iop.org/;
- DOI
- 10.1088/0953-8984/16/43/025;
- PII
- S0953-8984(04)78481-7;
Publishing Information
- Journal Title
- Journal of Physics. Condensed Matter
- Journal Volume
- 16
- Journal Issue
- 43
- Journal Page Range
- p. 7863-7871
- ISSN
- 0953-8984
- CODEN
- JCOMEL
INIS
- Country of Publication
- United Kingdom
- Country of Input or Organization
- International Atomic Energy Agency (IAEA)
- INIS RN
- 36033840
- Subject category
- S75: CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND SUPERFLUIDITY;
- Descriptors DEI
- ANTIFERROMAGNETISM; BRONZE; COULOMB ENERGY; CRITICAL TEMPERATURE; ELECTRIC CONDUCTIVITY; ELECTRONS; FERMI LEVEL; FLUCTUATIONS; HUBBARD MODEL; LAYERS; MAGNETIC PROPERTIES; PHASE TRANSFORMATIONS; RENORMALIZATION; SPIN; TEMPERATURE DEPENDENCE; VALENCE; VANADIUM; VANADIUM OXIDES
- Descriptors DEC
- ALLOYS; ANGULAR MOMENTUM; CHALCOGENIDES; COPPER ALLOYS; COPPER BASE ALLOYS; CRYSTAL MODELS; ELECTRICAL PROPERTIES; ELEMENTARY PARTICLES; ELEMENTS; ENERGY; ENERGY LEVELS; FERMIONS; LEPTONS; MAGNETISM; MATHEMATICAL MODELS; METALS; OXIDES; OXYGEN COMPOUNDS; PARTICLE PROPERTIES; PHYSICAL PROPERTIES; THERMODYNAMIC PROPERTIES; TIN ALLOYS; TRANSITION ELEMENT ALLOYS; TRANSITION ELEMENT COMPOUNDS; TRANSITION ELEMENTS; TRANSITION TEMPERATURE; VANADIUM COMPOUNDS; VARIATIONS