Published November 1997 | Version v1
Journal article Metadata-only

Crystal structure of di-μ-chloro-bis[(chloro-(aqua)-1-ethyl-2,3-bis (N-methylcarbamoyl cadmium], Cd2Cl4(AET)2)H2O)2

Creators

  • 1. Gruzinskij Tekhnicheskij Univ., Tbilisi (Greece)
  • 2. Inst. FizIki Tverdogo Tela AN Moldavii, Kishinev (Moldova, Republic of)

Description

Crystal structure of the crystals Cd2Cl4(Aet)2(H1)2, where AET=C9H16N4O2-ethymisol, has been decoded. The crystals are monoclinic: a=18.19 (1), b=16.59 (2), c=8.153 (6) A, γ=554.52 (2) deg, sp.gr. B2/b, Z=4. The crystal is built of dimeric central symmetric complexes [Cd2Cl4(AET)2(H2O)2]. Cl (2) atom performs the bridge function. Coordination polyhedron of Cd2+ ion is a distorted octahedron formed at the expense of three Cl atoms (two bridge and one terminal atoms), O (1) atom of H2O molecule, N (1) and O (3) atoms of ligand, AET. The distances are: Cd-Cl (1) 2.474 (2), Cd-Cl (2), 2.546 (2), Cd-O (1), 2.414 (6), Cd-N (1)AET 2.253 (6) and Cd-O(3)AET 2.513 (5) A

Additional details

Additional titles

Original title (Russian)
Kristallicheskaya struktura di-μ-khloro-bic-[(khloro)(akva)-1-ehtil-2,3-bic(N-metilkarbamoil)kadmiya] Cd

Publishing Information

Journal Title
Zhurnal Neorganicheskoj Khimii
Journal Volume
42
Journal Issue
11
Journal Page Range
p. 1858-1861
ISSN
0044-457X
CODEN
ZNOKAQ

INIS

Country of Publication
Russian Federation
Country of Input or Organization
Russian Federation
INIS RN
29043281
Subject category
S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
Descriptors DEI
BOND ANGLE; CADMIUM COMPLEXES; CHEMICAL BONDS; CHEMICAL COMPOSITION; CHEMICAL PREPARATION; CHLORIDES; INTERATOMIC DISTANCES; LATTICE PARAMETERS; MONOCLINIC LATTICES; ORGANIC NITROGEN COMPOUNDS; SPACE GROUPS
Descriptors DEC
CHLORINE COMPOUNDS; COMPLEXES; CRYSTAL LATTICES; CRYSTAL STRUCTURE; DISTANCE; HALIDES; HALOGEN COMPOUNDS; ORGANIC COMPOUNDS; SYMMETRY GROUPS; SYNTHESIS

Optional Information

Notes
4 refs., 4 tabs.