Published August 1, 1974 | Version v1
Journal article

Spin-other-orbit and spin--spin interactions in the metastable, c 3PI/subu/(1s,2p) state of H2

Creators

  • 1. Applied Physics Laboratory, The Johns Hopkins University, Silver Spring, Maryland 20910

Description

An ab initio calculation of the spin-other-orbit and spin-spin interactions in the c 3Πu(1s,2p) state of molecular hydrogen has been made. This calculation utilized the wavefunction obtained with the optimal double configuration model by Zemke, Lykos, and Wahl. The coupling constants are in good agreement with those calculated by Lombardi using the 45–50 configuration elliptic coordinate wavefunction of Rothenberg and Davidson.

Additional details

Identifiers

Publishing Information

Journal Title
The Journal of Chemical Physics
Journal Volume
61
Journal Issue
3
Series
J. Chem. Phys.
Journal Page Range
816-819
ISSN
0021-9606

INIS

Country of Publication
United States
Country of Input or Organization
United States
INIS RN
6155945
Subject category
S74: ATOMIC AND MOLECULAR PHYSICS;
Descriptors DEI
FINE STRUCTURE; HYDROGEN; HYPERFINE STRUCTURE; J-J COUPLING; L-S COUPLING; METASTABLE STATES; WAVE FUNCTIONS
Descriptors DEC
COUPLING; ELEMENTS; ENERGY LEVELS; EXCITED STATES; FUNCTIONS; INTERMEDIATE COUPLING; NONMETALS

Optional Information

Notes
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