Published November 1988 | Version v1
Journal article Metadata-only

Kinetic method of rhenium determination by nitrate-induced oxidation of diphenylamine with hydroxylamine

Creators

  • 1. AN SSSR, Moscow (USSR). Inst. Geokhimii i Analiticheskoj Khimii

Description

A nitrate-induced oxidation of diphenylamine by hydroxylamine catalyzed by oxochloride complex of rhenium (6) was found. An optimal ratio of concentrated. H2SO4 and HCl (3:1) was established which provided equilibrium existence of oxochloride complexes of Re(7), Re(6) and Re(5). A kinetic method was developed of determining rhenium in sulfuric acid solutions by using a rhenium-catalyzed HNO3-induced oxidation of diphenylamine with hydroxylamine. The limit of Re detection is 3.10-9 mole/l

Additional details

Additional titles

Original title (Russian)
Кинетический метод определения рения по реакции окисления дифениламина гидроксиламином, индуцируемой нитрат-ионом

Publishing Information

Journal Title
Zhurnal Analiticheskoj Khimii
Journal Volume
43
Journal Issue
11
Series
Zh. Anal. Khim.
Journal Page Range
2018-2023
ISSN
0044-4502
CODEN
ZAKHA

INIS

Country of Publication
Russian Federation
Country of Input or Organization
USSR
INIS RN
20044009
Subject category
S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
Descriptors DEI
ACCURACY; AMINES; CATALYSIS; CHEMICAL REACTION KINETICS; INORGANIC ACIDS; OXIDATION; OXYCHLORIDES; QUANTITATIVE CHEMICAL ANALYSIS; QUANTITY RATIO; REDUCTION; RHENIUM COMPLEXES; SENSITIVITY; TRACE AMOUNTS; VALENCE
Descriptors DEC
CHEMICAL ANALYSIS; CHEMICAL REACTIONS; CHLORINE COMPOUNDS; COMPLEXES; HALOGEN COMPOUNDS; HYDROGEN COMPOUNDS; INORGANIC COMPOUNDS; KINETICS; ORGANIC COMPOUNDS; OXYGEN COMPOUNDS; REACTION KINETICS; TRANSITION ELEMENT COMPLEXES