Published November 1993 | Version v1
Journal article Metadata-only

The oxidation of alcohols and aldehydes by potassium chlorate in te presence of a ruthenium heteropolycomplex

Creators

  • 1. AN SSSR, Novosibirsk (Russian Federation). Inst. Kataliza

Description

At interaction of K2RuOHCl5 with Na2PW11O39 catalyst for oxidation of primary alcohols and adlehydes up to proper carboxylic acid (yield ∼ 100%) was formed in aqueous solution, pH 2; 25-75 deg C. Acroleinwas demonstrated to be oxidized in acrylic acid with high selectivity

Additional details

Additional titles

Original title (Russian)
Окисление спиртов и альдегидов хлоратом калия в присутствии гетерополикомплекса рутения

Publishing Information

Journal Title
Kinetika i Kataliz
Journal Volume
34
Journal Issue
6
Journal Page Range
p. 1017-1019.
ISSN
0453-8811
CODEN
KNKTA4

INIS

Country of Publication
Russian Federation
Country of Input or Organization
Russian Federation
INIS RN
25069039
Subject category
S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
Descriptors DEI
ALCOHOLS; ALDEHYDES; CATALYSTS; CHEMICAL PREPARATION; CHEMICAL REACTION KINETICS; CHEMICAL REACTION YIELD; CHLORATES; HETEROPOLYANIONS; OXIDATION; PHOSPHORUS COMPOUNDS; RUTHENIUM COMPLEXES; TUNGSTEN COMPLEXES
Descriptors DEC
ANIONS; CHARGED PARTICLES; CHEMICAL REACTIONS; CHLORINE COMPOUNDS; COMPLEXES; HALOGEN COMPOUNDS; HYDROXY COMPOUNDS; IONS; KINETICS; ORGANIC COMPOUNDS; OXYGEN COMPOUNDS; REACTION KINETICS; SYNTHESIS; TRANSITION ELEMENT COMPLEXES; YIELDS