Published September 1, 1993 | Version v1
Journal article Metadata-only

Investigation of extraction and back-extraction behaviour of platinum(IV) with rubeanic acid in tributyl phosphate, with tributyl phosphate and with thenoyltrifluoroacetone in n-butyl alcohol-acetophenone by means of platinum-191 radiotracer for platinum-enrichment purposes

Creators

  • 1. Laboratory of Analytical Chemistry, Institute for Nuclear Sciences, University of Ghent, Ghent (Belgium)
  • 2. Institut fuer Spektrochemie und Angewandte Spektroskopie, Dortmund (Germany)

Description

Using 191Pt radiotracer, the liquid-liquid extraction behaviour of Pt(IV) from HCl medium with rubeanic acid in tributyl phosphate (TBP), with tributyl phosphate and with thenoyltrifluoroacetone (TTA) in n-butyl alcohol-acetophenone was examined. The effects of acidity, shaking time and Pt concentration were studied, in addition to the subsequent back-extraction. Optimum extraction recoveries were found when using 3 M HCl for TBP and 4 M HCl for TTA. Ammonia solution (2 M) yielded the best recovery for back-extraction. In order to evaluate the procedure in the presence of a matrix, some biological and environmental materials were spiked with 191Pt and the recovery of the radiotracer in the different steps was investigated

Additional details

Publishing Information

Journal Title
Analytica Chimica Acta
Journal Volume
281
Journal Issue
1
Journal Page Range
p. 153-160.
ISSN
0003-2670
CODEN
ACACAM

INIS

Country of Publication
Netherlands
Country of Input or Organization
Netherlands
INIS RN
25000091
Subject category
S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
Descriptors DEI
AMMONIA; CONCENTRATION RATIO; HYDROCHLORIC ACID; PH VALUE; PLATINUM IONS; PLATINUM 191; SOLVENT EXTRACTION; TBP; TTA
Descriptors DEC
BETA DECAY RADIOISOTOPES; BUTYL PHOSPHATES; CHARGED PARTICLES; CHLORINE COMPOUNDS; DAYS LIVING RADIOISOTOPES; ELECTRON CAPTURE RADIOISOTOPES; ESTERS; EVEN-ODD NUCLEI; EXTRACTION; HALOGEN COMPOUNDS; HEAVY NUCLEI; HETEROCYCLIC COMPOUNDS; HYDRIDES; HYDROGEN COMPOUNDS; INORGANIC ACIDS; INORGANIC COMPOUNDS; IONS; ISOTOPES; KETONES; NITROGEN HYDRIDES; NUCLEI; ORGANIC COMPOUNDS; ORGANIC FLUORINE COMPOUNDS; ORGANIC HALOGEN COMPOUNDS; ORGANIC SULFUR COMPOUNDS; PHOSPHORIC ACID ESTERS; PLATINUM ISOTOPES; RADIOISOTOPES; SEPARATION PROCESSES