Published April 2008 | Version v1
Journal article Metadata-only

Re-determination of the pseudobinary system Li2O-MoO3

Creators

  • 1. Humboldt-Universitaet zu Berlin, Institut fuer Chemie, Berlin (Germany)
  • 2. Institute for Crystal Growth, Berlin (Germany)

Description

The quasi-binary phase diagram lithium oxide - molybdenum(VI) oxide was investigated by differential scanning calorimetry and X-ray diffraction. The four intermediate phases Li4MoO5, Li2MoO4, Li4Mo5O17, and Li2Mo4O13 show incongruent melting. The system has one eutectic point at 50.5 mol% MoO3 and 49.5 mol% LiO0.5 with a eutectic temperature of 524.6 C. At this point the melt is in equilibrium with Li2MoO4 and Li4Mo5O17. (copyright 2008 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim) (orig.)

Availability note (English)

Available from: http://dx.doi.org/10.1002/crat.200711106

Additional details

Identifiers

DOI
10.1002/crat.200711106;
arXiv
arXiv:1108.3248v1;

Publishing Information

Journal Title
Crystal Research and Technology
Journal Volume
43
Journal Issue
4
Journal Page Range
p. 350-354
ISSN
0232-1300
CODEN
CRTEDF

INIS

Country of Publication
Germany
Country of Input or Organization
Germany
INIS RN
39063476
Subject category
S36: MATERIALS SCIENCE;
Descriptors DEI
BINARY MIXTURES; EUTECTICS; LITHIUM OXIDES; MELTING; MOLYBDATES; MOLYBDENUM OXIDES; PHASE DIAGRAMS; TEMPERATURE RANGE 0400-1000 K; THERMAL EQUILIBRIUM; X-RAY DIFFRACTION
Descriptors DEC
ALKALI METAL COMPOUNDS; CHALCOGENIDES; COHERENT SCATTERING; DIAGRAMS; DIFFRACTION; DISPERSIONS; EQUILIBRIUM; INFORMATION; LITHIUM COMPOUNDS; MIXTURES; MOLYBDENUM COMPOUNDS; OXIDES; OXYGEN COMPOUNDS; PHASE TRANSFORMATIONS; REFRACTORY METAL COMPOUNDS; SCATTERING; TEMPERATURE RANGE; TRANSITION ELEMENT COMPOUNDS

Optional Information

Notes
With 2 figs., 1 tab., 20 refs.. SICI: 0232-1300(200804)43:4<350::AID-CRAT200711106>3.0.TX;2-S