The microstructure and precipitation kinetics of a cast aluminium alloy

The microstructure of a cast Al-Si-Cu alloy was studied quantitatively in detail by a combination of differential scanning calorimetry, scanning electron microscopy, scanning tunnelling microscopy and transmission electron microscopy. The kinetics of coarsening can be described by the classical ripening theory. The plot of the rate constant of coarsening and the temperature follows an Arrhenius behaviour with an activation energy of about 140.4 kJ/mol-1, which is approximately the activation energy for diffusion of Cu and/or Si in Al, indicating diffusion-controlled precipitate growth