Yield of electronically excited CN molecules from the dissociative recombination of HNC+ with electrons

The authors have studied CN(B-X) and CN(A-X) emissions produced by the dissociative recombination of HNC+ ions with thermal electrons in a flowing afterglow experiment. A separate drift tube study showed that the reaction Ar++HCN, the precursor reaction used in the flow-tube experiment, produces predominantly HNC+ rather than the more energetic HCN+ isomer. Models simulating the ion-chemical processes, diffusion, and gas mixing in the afterglow plasma were fitted to observed position dependent CN(A-X) and CN(B-X) band intensities. Absolute yields of CN(B) and CN(A) were then obtained by comparing the CN band intensities to those of CO bands produced by recombination of CO2+ ions. It was concluded that the 300 K recombination coefficient of HNC+ is close to 2x10-7 cm3 s-1, that CN(B) is formed with a yield of 0.22±0.08 and CN(A) with a yield of 0.14±0.05. By comparison to synthetic spectra, the rotational temperature of CN(B) was estimated to be approximately 2500 K. It was also found that recombination produces CN(B) and CN(A) with far greater vibrational excitation than would be expected from the ''impulse model'' of Bates [Mon. Not. R. Astron. Soc. 263, 369 (1993)]