Published September 11, 2012 | Version v1
Journal article

Optimal control of the inversion of two spins in Nuclear Magnetic Resonance

  • 1. Laboratoire Interdisciplinaire Carnot de Bourgogne (ICB), UMR 6303 CNRS-Université de Bourgogne, 9 Av. A. Savary, BP 47 870, F-21078 DIJON Cedex (France)
  • 2. Institut de Chimie Moléculaire de l'Université de Bourgogne (ICMUB), UMR 6302 CNRS-Université de Bourgogne, 9 Av. A. Savary, BP 47 870, F-21078 DIJON Cedex (France)
  • 3. Department of Chemistry, Technische Universität München, Lichtenbergstrasse 4, D-85747 Garching (Germany)

Description

Highlights: ► We investigate the simultaneous optimal control of the inversion of two spins. ► We examine the energy minimum solution. ► We compare this solution with the time-minimum one. ► Experimental implementation using techniques of Nuclear Magnetic Resonance. -- Abstract: We investigate the optimal control of the inversion of two spin 1/2 particles in Nuclear Magnetic Resonance. The two spins, which differ by their resonance offset, are controlled by the same radio frequency magnetic field. Using the Pontryagin Maximum Principle, we compute the optimal control sequence which allows to reach the target state in a given time, while minimizing the energy of the magnetic field. A comparison with the time-optimal solution for bounded control amplitude realizing the same control in the same time is made. An experimental illustration is done using techniques of Nuclear Magnetic Resonance.

Availability note (English)

Available from http://dx.doi.org/10.1016/j.chemphys.2012.06.013

Additional details

Identifiers

DOI
10.1016/j.chemphys.2012.06.013;
PII
S0301-0104(12)00262-5;

Publishing Information

Journal Title
Chemical Physics
Journal Volume
405
Journal Page Range
p. 71-75
ISSN
0301-0104
CODEN
CMPHC2

Optional Information

Copyright
Copyright (c) 2012 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved.