Optimal control of the inversion of two spins in Nuclear Magnetic Resonance
Creators
- 1. Laboratoire Interdisciplinaire Carnot de Bourgogne (ICB), UMR 6303 CNRS-Université de Bourgogne, 9 Av. A. Savary, BP 47 870, F-21078 DIJON Cedex (France)
- 2. Institut de Chimie Moléculaire de l'Université de Bourgogne (ICMUB), UMR 6302 CNRS-Université de Bourgogne, 9 Av. A. Savary, BP 47 870, F-21078 DIJON Cedex (France)
- 3. Department of Chemistry, Technische Universität München, Lichtenbergstrasse 4, D-85747 Garching (Germany)
Description
Highlights: ► We investigate the simultaneous optimal control of the inversion of two spins. ► We examine the energy minimum solution. ► We compare this solution with the time-minimum one. ► Experimental implementation using techniques of Nuclear Magnetic Resonance. -- Abstract: We investigate the optimal control of the inversion of two spin 1/2 particles in Nuclear Magnetic Resonance. The two spins, which differ by their resonance offset, are controlled by the same radio frequency magnetic field. Using the Pontryagin Maximum Principle, we compute the optimal control sequence which allows to reach the target state in a given time, while minimizing the energy of the magnetic field. A comparison with the time-optimal solution for bounded control amplitude realizing the same control in the same time is made. An experimental illustration is done using techniques of Nuclear Magnetic Resonance.
Availability note (English)
Available from http://dx.doi.org/10.1016/j.chemphys.2012.06.013Additional details
Identifiers
- DOI
- 10.1016/j.chemphys.2012.06.013;
- PII
- S0301-0104(12)00262-5;
Publishing Information
- Journal Title
- Chemical Physics
- Journal Volume
- 405
- Journal Page Range
- p. 71-75
- ISSN
- 0301-0104
- CODEN
- CMPHC2
INIS
- Country of Publication
- Netherlands
- Country of Input or Organization
- International Atomic Energy Agency (IAEA)
- INIS RN
- 45027547
- Subject category
- S74: ATOMIC AND MOLECULAR PHYSICS;
- Descriptors DEI
- AMPLITUDES; COMPARATIVE EVALUATIONS; ENERGY LEVELS; FERMIONS; IMPLEMENTATION; MAGNETIC FIELDS; MATHEMATICAL SOLUTIONS; NUCLEAR MAGNETIC RESONANCE; OPTIMAL CONTROL; RADIOWAVE RADIATION; SPIN; SPIN ORIENTATION
- Descriptors DEC
- ANGULAR MOMENTUM; CONTROL; ELECTROMAGNETIC RADIATION; EVALUATION; MAGNETIC RESONANCE; ORIENTATION; PARTICLE PROPERTIES; RADIATIONS; RESONANCE
Optional Information
- Copyright
- Copyright (c) 2012 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved.