Published May 2002 | Version v1
Journal article

γ-Radiation effects on colourless silicates of beryl

Description

γ-Ray radiation effects on thermoluminescence (TL), electron spin resonance (ESR) and optical absorption (OA) properties of natural uncoloured beryl (Be3Al2Si6O18) were investigated. All the TL glow curves for annealed and subsequently irradiated samples showed a single peak at 165 deg. C. This TL peak did not indicate any relation with the H0 center, contrary to the TL process proposed for beryl. Irradiation with 106 Gy plainly enhanced the following in the samples: the so-called 'Maxixe' bands at 600-700 nm due to CO3-; an OA band at 315-326 nm which can be assigned to ultraviolet charge transfer (UVCT) from O2- to Fe3+ in the tetrahedral Be2+ site, and an ESR signal of Fe3+ observed at g=4.257. An isochronal thermal anneal study indicated a certain correlation between the OA band at 315-326 nm and the ESR signal of Fe3+. The UVCT process of this OA band is related to Fe3+, and hence the observed correlation is considered to be reasonable

Additional details

Identifiers

PII
S0168583X02005761;

Publishing Information

Journal Title
Nuclear Instruments and Methods in Physics Research. Section B, Beam Interactions with Materials and Atoms
Journal Volume
191
Journal Issue
1-4
Journal Page Range
p. 281-284
ISSN
0168-583X
CODEN
NIMBEU

Optional Information

Copyright
Copyright (c) 2002 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved.