Published 2002
| Version v1
Miscellaneous
Synthesis and structure of Sr-doped rare earth cobaltates
- 1. Australian Nuclear Science and Technology Organisation, Menai, NSW (Australia)
- 2. Australian National University, Canberra, ACT (Australia)
Description
Full text: Materials based on the basic perovskite structure, CaTiO3δ show a vast range of physical properties, including high temperature superconductivity and colossal magneto-resistance. Here a structural study of the M1-xSrxCoO3-δ family of oxides, where M is Y3+ or a lanthanide ion and x = 2/3 is presented. The samples were synthesized using sol-gel methods and sintered in air. The solid solution range is outlined, both in terms of x and M. The existence of supercell reflections is demonstrated, and electron diffraction and synchrotron and laboratory X-ray diffraction shows the structure to be pseudo-tetragonal, with space group Cmmm and lattice parameters approximately 2√2a, 2√2a, 4a where a is the basic perovskite lattice vector
Additional details
Publishing Information
- Imprint Title
- 15th Biennial Congress of the Australian Institute of Physics incorporating Australian Conference of Optical Fibre Technology (ACOFT) and Australian Optical Society (AOS). Handbook and abstracts
- Imprint Pagination
- 235 p.
- Journal Page Range
- p. 183-184
Conference
- Title
- 15. Biennial Congress of the Australian Institute of Physics. Physics and industry working together
- Dates
- 8-11 Jul 2002
- Place
- Sydney, NSW (Australia)
INIS
- Country of Publication
- Australia
- Country of Input or Organization
- Australia
- INIS RN
- 36063525
- Subject category
- S36: MATERIALS SCIENCE;
- Resource subtype / Literary indicator
- Conference, Non-conventional Literature
- Descriptors DEI
- COBALT OXIDES; CRYSTAL STRUCTURE; DOPED MATERIALS; ELECTRON DIFFRACTION; LATTICE PARAMETERS; ORTHORHOMBIC LATTICES; PEROVSKITES; SOL-GEL PROCESS; SOLID SOLUTIONS; SPACE GROUPS; STRONTIUM; SUPERCONDUCTIVITY; SYNCHROTRON RADIATION; SYNTHESIS; TEMPERATURE RANGE 0400-1000 K; X-RAY DIFFRACTION; YTTRIUM OXIDES
- Descriptors DEC
- ALKALINE EARTH METALS; BREMSSTRAHLUNG; CHALCOGENIDES; COBALT COMPOUNDS; COHERENT SCATTERING; CRYSTAL LATTICES; CRYSTAL STRUCTURE; DIFFRACTION; DISPERSIONS; ELECTRIC CONDUCTIVITY; ELECTRICAL PROPERTIES; ELECTROMAGNETIC RADIATION; ELEMENTS; HOMOGENEOUS MIXTURES; MATERIALS; METALS; MINERALS; MIXTURES; OXIDES; OXYGEN COMPOUNDS; PHYSICAL PROPERTIES; RADIATIONS; SCATTERING; SOLUTIONS; SYMMETRY GROUPS; TEMPERATURE RANGE; TRANSITION ELEMENT COMPOUNDS; YTTRIUM COMPOUNDS