Mechanism of peroxymonosulfate activation and the utilization efficiency using hollow (Co, Mn)3O4 nanoreactor as an efficient catalyst for degradation of organic pollutants

Development of efficient catalysts for peroxymonosulfate (PMS) activation and further understanding its mechanism on organic pollutants degradation is of significant importance for advanced oxidation processes (AOPs). Herein, hollow (Co, Mn)₃O₄ catalysts were synthesized by calcination of Co, Mn containing metal-organic frameworks (MOFs) and further used to evaluate the effectiveness of organic pollutants (Bisphenol A (BPA), atrazine (ATZ), and diethyl phthalate (DEP)) degradation by PMS activation. The PMS utilization efficiency in (Co, Mn)₃O₄/PMS system (36.4%) was estimated to be 28.0% and 43.8% higher than that of Co₃O₄/PMS and Mn₅O₈/PMS system, respectively. Notably, the metal leaching in (Co, Mn)₃O₄/PMS system was significantly suppressed. The utilization efficiency also reveals an inverse proportionality relationship with BPA mineralization but decreases with increasing initial pH value. A synergy between oxides of Co and Mn was perceived to enhance PMS utilization efficiency and BPA degradation. The results indicate enhanced catalytic performance with (Co, Mn)₃O₄ compared to Co₃O₄ derived from Co-MOF and other reported catalysts, with 99% of BPA degradation within 4 min. The oxidation mechanism was then proposed based on the electron paramagnetic resonance (EPR) and XPS results. Our findings might have contributed to designing heterogeneous catalysts for efficient PMS utilization in AOPs.